Redox-active ligands–a viable route to reactive main group metal compounds

GG Briand - Dalton Transactions, 2023 - pubs.rsc.org
Anionic redox-active ligands such as o-amidophenolates, catecholates, dithiolenes, 1, 2-
benzendithiolates, 2-amidobenzenethiolates, reduced α-diimines, ferrocenyl and …

Expanding the Scope of Aluminum Chemistry with Noninnocent Ligands

LWT Parsons, LA Berben - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Aluminum is the most abundant metal in the earth's crust at 8%, and it is also
widely available domestically in many countries worldwide, which ensures a stable supply …

Group 13 ion coordination to pyridyl models NAD+ reduction potentials

LWT Parsons, JC Fettinger, LA Berben - Chemical Communications, 2023 - pubs.rsc.org
N-alkylation and N-metallation of pyridine are explored herein to understand how metal-
ligand complexes can model NAD+ redox chemistry. Syntheses of substituted …

Controlling intramolecular and intermolecular electronic coupling of radical ligands in a series of cobaltoviologen complexes

BJO Kessler, IF Mansoor, DI Wozniak… - Journal of the …, 2023 - ACS Publications
Controlling electronic coupling between multiple redox sites is of interest for tuning the
electronic properties of molecules and materials. While classic mixed-valence (MV) systems …

Enabling Valence Delocalization in Iron (III) Macrocyclic Complexes through Ring Unsaturation

RA Clendening, SS Delancey, AT Poore… - Inorganic …, 2023 - ACS Publications
The complexes [FeIII (HMC)(C2DMA) 2] CF3SO3 ([2] OTf) and [FeIII (HMTI)(C2Y) 2] CF3SO3
([3a–c] OTf) have been prepared and thoroughly characterized (HMC= 5, 5, 7, 12, 12, 14 …

[PDF][PDF] ペンダントアーム型配位子を有する新規p-ブロック化合物の合成とその配位子の開発

イトウダイチ, 伊藤大地 - tokyo-metro-u.repo.nii.ac.jp
化学という学問域の中の一つである有機化学は, 有機化合物の構造・物性・反応性だけでなく,
それらが有する機能性の探索, ならびにその応用を取り扱う分野である. 有機化合物の骨格は主に …