Recent Progress on the synthesis of bipyridine derivatives

Y Yamanoi - Molecules, 2024 - mdpi.com
Bipyridine and related compounds are starting materials or precursors for a variety of
valuable substances such as biologically active molecules, ligands for catalysts …

Dihydropyridine preparation and application in the synthesis of pyridine derivatives

DL Comins, K Higuchi, DW Young - Advances in Heterocyclic Chemistry, 2013 - Elsevier
The preparation and application of dihydropyridines continue to attract considerable interest
in organic synthesis and medicinal chemistry. The biological activities and synthetic utility of …

New hindered amide base for Aryne insertion into Si–P, Si–S, Si–N, and C–C bonds

M Mesgar, J Nguyen-Le, O Daugulis - Journal of the American …, 2018 - ACS Publications
A general method for a new, hindered lithium diadamantylamide (LDAM) base-promoted
insertion of arynes into Si–P, Si–S, Si–N, and C–C bonds is described. Arynes are …

3, 7‐Diazadibenzophosphole oxide: a phosphorus‐bridged viologen analogue with significantly lowered reduction threshold

S Durben, T Baumgartner - Angewandte Chemie International …, 2011 - Wiley Online Library
4, 4'-Bipyridine (1) and its N-alkylated congeners [1] are classic organic building blocks that
have been utilized in a variety of fields, such as photochemistry,[1b] electrochemistry,[1c] …

Base-Mediated Intermolecular sp2 C−H Bond Arylation via Benzyne Intermediates

T Truong, O Daugulis - Journal of the American Chemical Society, 2011 - ACS Publications
A transition-metal-free method for arylation of heterocycle and arene carbon− hydrogen
bonds by aryl chlorides and fluorides has been developed. The reactions proceed via aryne …

General method for functionalized polyaryl synthesis via aryne intermediates

T Truong, M Mesgar, KKA Le… - Journal of the American …, 2014 - ACS Publications
A method for base-promoted arylation of arenes and heterocycles by aryl halides and aryl
triflates is described. Additionally, in situ electrophilic trapping of ArLi intermediates …

Enantioseparation of 5, 5′-dibromo-2, 2′-dichloro-3-selanyl-4, 4′-bipyridines on polysaccharide-based chiral stationary phases: Exploring chalcogen bonds in …

P Peluso, A Dessì, R Dallocchio, B Sechi, C Gatti… - Molecules, 2021 - mdpi.com
The chalcogen bond (ChB) is a noncovalent interaction based on electrophilic features of
regions of electron charge density depletion (σ-holes) located on bound atoms of group VI …

Hydroarylation of arynes catalyzed by silver for biaryl synthesis

NK Lee, SY Yun, P Mamidipalli… - Journal of the …, 2014 - ACS Publications
A new biaryl synthesis via silver-catalyzed hydroarylation of arynes from acyclic building
blocks with unactivated arenes in intra-and intermolecular manners has been developed …

[HTML][HTML] Enantioseparation of new axially chiral carboxylic acids on polysaccharide-based chiral stationary phases under normal phase elution conditions

B Sechi, V Mamane, R Dallocchio, A Dessì… - … of Pharmaceutical and …, 2023 - Elsevier
In the last decade, the availability of new and versatile synthetic strategies for the
preparation of substituted 4, 4'-bipyridyl derivatives based on chemo-and regioselective …

Polysaccharide‐based chiral stationary phases as halogen bond acceptors: A novel strategy for detection of stereoselective σ‐hole bonds in solution

P Peluso, V Mamane, R Dallocchio… - Journal of separation …, 2018 - Wiley Online Library
In the last few years, halogen bonds have been exploited in a variety of research areas both
in the solid state and in solution. Nevertheless, several factors make formation and detection …