Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …
One-Dimensional Diiodine–Iodobismuthate(III) Hybrids Cat3{[Bi2I9](I2)3}: Syntheses, Stability, and Optical Properties
AN Usoltsev, NA Korobeynikov, AS Novikov… - Inorganic …, 2020 - ACS Publications
One-dimensional iodine-rich iodobismuthates (III), Cat3 {[Bi2I9](I2) 3}[Cat= 1, 4-MePy (1)
and 1-EtBMAP (2)], feature the highest amount of “trapped” diiodine units in polyhalogen …
and 1-EtBMAP (2)], feature the highest amount of “trapped” diiodine units in polyhalogen …
Bifurcated halogen bonding involving diaryliodonium cations as iodine (III)-based double-σ-hole donors
IS Aliyarova, DM Ivanov, NS Soldatova… - Crystal Growth & …, 2021 - ACS Publications
Three diaryliodonium tetrachloroaurates (III),[Ar1IAr2][AuCl4](Ar1/Ar2= Ph/Ph (1), Ph/Mes
(2), o-(C6H4) 2 (3)), were obtained as solids (62–80%) by the metathetical reaction of …
(2), o-(C6H4) 2 (3)), were obtained as solids (62–80%) by the metathetical reaction of …
Difference in Energy between Two Distinct Types of Chalcogen Bonds Drives Regioisomerization of Binuclear (Diaminocarbene)PdII Complexes
The reaction of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with various 1, 3-thiazol-and 1, 3,
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
Hexaiododiplatinate (ii) as a useful supramolecular synthon for halogen bond involving crystal engineering
Hexaiododiplatinates (II) bearing ammonium and phosphonium cations,[R4N] 2 [Pt2 (μ-I)
2I4]{R= Et (1) and n-Bu (2)} and [R3PR1] 2 [Pt2 (μ-I) 2I4]{R= n-Bu and R1= n-Bu (3); R= Ph …
2I4]{R= Et (1) and n-Bu (2)} and [R3PR1] 2 [Pt2 (μ-I) 2I4]{R= n-Bu and R1= n-Bu (3); R= Ph …
Electrophilic–nucleophilic dualism of nickel (II) toward Ni··· I noncovalent interactions: Semicoordination of iodine centers via electron belt and halogen bonding via σ …
ZM Bikbaeva, DM Ivanov, AS Novikov… - Inorganic …, 2017 - ACS Publications
The nitrosoguanidinate complex [Ni {NH C (NMe2) NN (O)} 2](1) was cocrystallized with I2
and sym-trifluorotriiodobenzene (FIB) to give associates 1· 2I2 and 1· 2FIB. Structures of …
and sym-trifluorotriiodobenzene (FIB) to give associates 1· 2I2 and 1· 2FIB. Structures of …
Recognition of the π-hole donor ability of iodopentafluorobenzene–a conventional σ-hole donor for crystal engineering involving halogen bonding
Iodopentafluorobenzene (IPFB or PhFI) was co-crystallized with tetra (n-butyl) ammonium
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …
A novel family of polyiodo‐bromoantimonate (III) complexes: cation‐driven self‐assembly of photoconductive metal‐polyhalide frameworks
SA Adonin, LI Udalova, PA Abramov… - … A European Journal, 2018 - Wiley Online Library
In the presence of different cations, reactions of [SbBr6] 3− and I2 result in a new family of
diverse supramolecular 1D polyiodide‐bromoantimonate networks. The coordination …
diverse supramolecular 1D polyiodide‐bromoantimonate networks. The coordination …
H2C(X)–X···X– (X = Cl, Br) Halogen Bonding of Dihalomethanes
The dihalomethane–halide H2C (X)–X··· X–(X= Cl, Br) halogen bonding was detected in a
series of the cis-[PdX (CNCy){C (NHCy) NHC6H2Me2 N H2}] X• CH2X2 (X= Cl, Br) …
series of the cis-[PdX (CNCy){C (NHCy) NHC6H2Me2 N H2}] X• CH2X2 (X= Cl, Br) …
Pt/Pd and I/Br isostructural exchange provides formation of C–I··· Pd, C–Br··· Pt, and C–Br··· Pd metal-involving halogen bonding
Complexes trans-[MCl2 (NCNMe2) 2](M= Pt 1, Pd 2) were cocrystallized with CHBr3 and
CHI3, forming 1: 2 adducts isomorphic with previously reported trans-[PtCl2 (NCNMe2) 2] …
CHI3, forming 1: 2 adducts isomorphic with previously reported trans-[PtCl2 (NCNMe2) 2] …