Designed metal-organic frameworks with potential for multi-component hydrocarbon separation

L Wang, H Huang, X Zhang, H Zhao, F Li… - Coordination Chemistry …, 2023 - Elsevier
Petrochemical-related gases, especially light hydrocarbons with 1–8 carbon atoms, are
essential industrial feedstocks. However, during steam cracking they inevitably coexist with …

Micro-and mesoporous metal-organic frameworks for hydrocarbon separation

KA Kovalenko, AS Potapov… - Russian Chemical Reviews, 2022 - iopscience.iop.org
The review presents data on the use of porous metal-organic frameworks for the separation
of some industrially important hydrocarbon mixtures, such as ethane and ethylene, propane …

Highly efficient separation of C8 aromatic isomers by rationally designed nonaromatic metal–organic frameworks

J Zhou, T Ke, Y Song, H Cai, Z Wang… - Journal of the …, 2022 - ACS Publications
The separation of C8 aromatics (xylenes and ethylbenzene) remains one of the most
challenging industrial separations due to their similar structures and properties. Suitable …

Selective Separation of C8 Aromatics by an Interpenetrating Metal–Organic Framework Material

N Sun, X Zhou, H Yu, X Si, F Ding, Y Sun… - Inorganic …, 2024 - ACS Publications
O-xylene (OX) is an important chemical raw material, but it is often produced in mixtures with
other C8 aromatics. Similar physicochemical properties of the C8 isomers make their …

Highly Selective p-Xylene Separation from Mixtures of C8 Aromatics by a Nonporous Molecular Apohost

M Rahmani, CRMO Matos, SQ Wang… - Journal of the …, 2023 - ACS Publications
High and increasing production of separation of C8 aromatic isomers demands the
development of purification methods that are efficient, scalable, and inexpensive, especially …

Fine-tuning window apertures in ZIF-8/67 frameworks by metal ions and temperature for high-efficiency molecular sieving of xylenes

DM Polyukhov, AS Poryvaev, AS Sukhikh… - … Applied Materials & …, 2021 - ACS Publications
Separation of structurally similar components from their mixtures is one of the most
promising applications of metal–organic frameworks (MOFs). A high efficiency of such …

Separation of xylene isomers using metal-organic frameworks: Addressing challenges in the petrochemical industry

Y Liu, C Wang, Q Yang, Q Ren, Z Bao - Coordination Chemistry Reviews, 2025 - Elsevier
The separation of xylene isomers remains a formidable challenge in the petrochemical
sector due to their subtle differences in the molecular structure and physicochemical …

Iodinated vs non-iodinated: Comparison of sorption selectivity by [Zn2 (bdc) 2dabco] n and superstructural 2-iodoterephtalate-based metal–organic framework

AS Zaguzin, TS Sukhikh, BA Kolesov, MN Sokolov… - Polyhedron, 2022 - Elsevier
Abstract [Zn 2 (2-I-bdc) 2 dabco] n metal–organic framework (2-I-bdc= 2-iodoterephtalate,
dabco= 1, 8-diazabicyclooctane](1) was prepared and structurally characterized as a …

The Complexity of Comparative Adsorption of C6 Hydrocarbons (Benzene, Cyclohexane, n-Hexane) at Metal–Organic Frameworks

C Jansen, N Assahub, A Spieß, J Liang, A Schmitz… - Nanomaterials, 2022 - mdpi.com
The relatively stable MOFs Alfum, MIL-160, DUT-4, DUT-5, MIL-53-TDC, MIL-53, UiO-66,
UiO-66-NH2, UiO-66 (F) 4, UiO-67, DUT-67, NH2-MIL-125, MIL-125, MIL-101 (Cr), ZIF-8, ZIF …

Selective Adsorption and Separation of o-Xylene Using an Aluminum-Based Metal–Organic Framework

Y Zhao, H Zhao, D Liu - Industrial & Engineering Chemistry …, 2021 - ACS Publications
Separation and purification of C8 aromatics is still a great challenge owing to their similar
boiling point and molecular size. Herein, an aluminum-based metal–organic framework was …