One of the simplest organic functional groups, the alkyne, offers a broad canvas for the
design of cascade transformations in which up to three new bonds can be added to each of …

Carbo-and heterocycles are widely found in natural products, biologically active structures,
medicinally relevant compounds, and in many other fine chemicals. The development of …

Cascade radical cyclization is an attractive synthetic method due to its high atom-and step-
economy to construct carbo-and heterocycles, which have wide applications in chemical …

A catalytic bicyclization reaction of 1, 5-enynes anchored by α, β-conjugates with arylsulfonyl
radicals generated in situ from sulfonyl hydrazides has been established using TBAI (20 …

Stable tricyclic aminoperoxides can be selectively assembled via a catalyst-free three-
component condensation of β, δ′-triketones, H2O2, and an NH-group source such as …

Aromatic organotin (IV) compounds are a valuable class of reagents widely used in cross-
coupling reactions. However, the toxicity of the most popular tributyl-substituted …

A new metal‐free radical 5‐exo‐dig cyclization of phenol‐linked 1, 6‐enynes with O2, 2, 2,
6, 6‐tetramethyl‐1‐piperidinyloxy (TEMPO), and tBuONO is described. With this general …

Cascade radical cyclization of 1, 6-enynes for the synthesis of biologically important γ-
lactams containing alkenyl C–X bonds is reported. In these radical cascade processes, three …

1, 3-Dien-5-ynes have been extensively used as starting materials for the synthesis of a
wide number of different carbo-and heterocycles. The aim of this review is to give an …

Radical addition to isonitriles (isocyanides) starts and continues all the way to the transition
state (TS) mostly as a simple addition to a polarized π-bond. Only after the TS has been …