The halogen bond
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
Principles and Applications of CF2X Moieties as Unconventional Halogen Bond Donors in Medicinal Chemistry, Chemical Biology, and Drug Discovery
S Vaas, MO Zimmermann, D Schollmeyer… - Journal of Medicinal …, 2023 - ACS Publications
As an orthogonal principle to the established (hetero) aryl halides, we herein highlight the
usefulness of CF2X (X= Cl, Br, or I) moieties. Using tool compounds bearing CF2X moieties …
usefulness of CF2X (X= Cl, Br, or I) moieties. Using tool compounds bearing CF2X moieties …
Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …
Breathing molecular crystals: halogen-and hydrogen-bonded porous molecular crystals with solvent induced adaptation of the nanosized channels
K Raatikainen, K Rissanen - Chemical Science, 2012 - pubs.rsc.org
Exceptionally strong (OC–) 2N–I⋯ N halogen bonding (XB) in a combination with CO⋯ H–C
hydrogen bonds (HB) between N-iodosuccinimide (NIS) and hexamethylenetetramine …
hydrogen bonds (HB) between N-iodosuccinimide (NIS) and hexamethylenetetramine …
Halogen bonding to amplify luminescence: a case study using a platinum cyclometalated complex
The cocrystallization of a weakly luminescent platinum complex [Pt (btpy)(PPh3)
Cl](1)(Hbtpy= 2‐(2benzothienyl) pyridine; emission quantum yield Φem= 0.03) with …
Cl](1)(Hbtpy= 2‐(2benzothienyl) pyridine; emission quantum yield Φem= 0.03) with …
Halogen and Hydrogen Bonding between (N‐Halogeno)‐succinimides and Pyridine Derivatives in Solution, the Solid State and In Silico
A study of strong halogen bonding within three series of halogen‐bonded complexes,
derived from seven para‐substituted pyridine derivatives and three N‐halosuccinimides …
derived from seven para‐substituted pyridine derivatives and three N‐halosuccinimides …
Alternative motifs for halogen bonding
RW Troff, T Mäkelä, F Topić, A Valkonen… - European Journal of …, 2013 - Wiley Online Library
The halogen‐bonding interaction is one of the rising stars in supramolecular chemistry.
Although other weak interactions and their influence on the structure and chemistry of …
Although other weak interactions and their influence on the structure and chemistry of …
Halogen bonding in the co-crystallization of potentially ditopic diiodotetrafluorobenzene: a powerful tool for constructing multicomponent supramolecular assemblies
Halogen bonding is emerging as a significant driving force for supramolecular self-assembly
and has aroused great interest during the last two decades. Among the various halogen …
and has aroused great interest during the last two decades. Among the various halogen …
A novel family of polyiodo‐bromoantimonate (III) complexes: cation‐driven self‐assembly of photoconductive metal‐polyhalide frameworks
SA Adonin, LI Udalova, PA Abramov… - … A European Journal, 2018 - Wiley Online Library
In the presence of different cations, reactions of [SbBr6] 3− and I2 result in a new family of
diverse supramolecular 1D polyiodide‐bromoantimonate networks. The coordination …
diverse supramolecular 1D polyiodide‐bromoantimonate networks. The coordination …
Noncovalent Interactions Involving Iodofluorobenzenes: The Interplay of Halogen Bonding and Weak lp(O)···π-Holearene Interactions
AS Novikov, DM Ivanov, ZM Bikbaeva… - Crystal Growth & …, 2018 - ACS Publications
Fluorinated iodoarenes such as 1, 4-diiodotetrafluorobenzene (1, 4-FIB) and 1, 3, 5-
triiodotrifluorobenzene (1, 3, 5-FIB) were cocrystallized with the nitrosoguanidinate-nickel (II) …
triiodotrifluorobenzene (1, 3, 5-FIB) were cocrystallized with the nitrosoguanidinate-nickel (II) …