Nanoarchitectonics: the method for everything in materials science

K Ariga - Bulletin of the Chemical Society of Japan, 2024 - academic.oup.com
Nanotechnology has revealed the science of the nanoscale. The global challenge that will
follow is to build functional materials with the knowledge of nanoscale phenomena. This task …

Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina, M Mendt… - Angewandte …, 2023 - Wiley Online Library
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

Pore modulation of hydrogen‐bonded organic frameworks for efficient separation of propylene

Y Cai, J Gao, JH Li, P Liu, Y Zheng, W Zhou… - Angewandte …, 2023 - Wiley Online Library
Developing hydrogen‐bonded organic frameworks (HOFs) that combine functional sites,
size control, and storage capability for targeting gas molecule capture is a novel and …

Topological design of unprecedented metal‐organic frameworks featuring multiple anion functionalities and hierarchical porosity for benchmark acetylene separation

Y Zhang, W Sun, B Luan, J Li, D Luo… - Angewandte Chemie …, 2023 - Wiley Online Library
Separation of acetylene (C2H2) from carbon dioxide (CO2) or ethylene (C2H4) is industrially
important but still challenging so far. Herein, we developed two novel robust metal organic …

Confining Water Nanotubes in a Cu10O13-Based Metal–Organic Framework for Propylene/Propane Separation with Record-High Selectivity

Q Dong, Y Huang, J Wan, Z Lu, Z Wang… - Journal of the …, 2023 - ACS Publications
Energy-efficient separation of propylene (C3H6)/propane (C3H8) is in high demand for the
chemical industry. However, this process is challenging due to the imperceptible difference …

A molecular sieve with ultrafast adsorption kinetics for propylene separation

J Cui, Z Zhang, L Yang, J Hu, A Jin, Z Yang, Y Zhao… - Science, 2024 - science.org
The design of molecular sieves is vital for gas separation, but it suffers from a long-standing
issue of slow adsorption kinetics due to the intrinsic contradiction between molecular sieving …

Potential of nonporous adaptive crystals for hydrocarbon separation

M Yan, Y Wang, J Chen, J Zhou - Chemical Society Reviews, 2023 - pubs.rsc.org
Hydrocarbon separation is an important process in the field of petrochemical industry, which
provides a variety of raw materials for industrial production and a strong support for the …

Delicate softness in a temperature-responsive porous crystal for accelerated sieving of propylene/propane

Y Huang, J Wan, T Pan, K Ge, Y Guo… - Journal of the …, 2023 - ACS Publications
Soft nanoporous crystals with structural dynamics are among the most exciting recently
discovered materials. However, designing or controlling a porous system with delicate …

Molecular recognition with resolution below 0.2 angstroms through thermoregulatory oscillations in covalent organic frameworks

Y Hu, B Sengupta, H Long, LJ Wayment, R Ciora, Y Jin… - Science, 2024 - science.org
Crystalline materials with uniform molecular-sized pores are desirable for a broad range of
applications, such as sensors, catalysis, and separations. However, it is challenging to tune …

Design of a four-atom cluster embedded in carbon nitride for electrocatalytic generation of multi-carbon products

D Zhang, OV Prezhdo, L Xu - Journal of the American Chemical …, 2023 - ACS Publications
The development of efficient and stable catalysts for the electrocatalytic CO2 and CO
reduction reactions (CORR) is under active investigation, but the problems of poor selectivity …