Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N-Donor Ligands

PJ Panak, A Geist - Chemical reviews, 2013 - ACS Publications
The transuranium elements (TRU) neptunium, plutonium, americium, and curium are
produced in nuclear fuel during reactor operation from neutron capture by uranium-235/238 …

The pyridyl group in ligand design for selective metal ion complexation and sensing

RD Hancock - Chemical Society Reviews, 2013 - pubs.rsc.org
Factors in polypyridyl ligands that control their thermodynamic metal ion selectivity in
aqueous solution, and their use in selective fluorescent sensing, are examined …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Separation of trivalent actinides and lanthanides using various 'N','S'and mixed 'N, O'donor ligands: a review

A Bhattacharyya, PK Mohapatra - Radiochimica Acta, 2019 - degruyter.com
Separation of trivalent actinide (An) and lanthanide (Ln) elements is one of the burning
topics in the back end of the nuclear fuel cycle due to the similarity in their chemical …

Development of highly selective ligands for separations of actinides from lanthanides in the nuclear fuel cycle

FW Lewis, MJ Hudson, LM Harwood - Synlett, 2011 - thieme-connect.com
This account summarizes recent work by us and others on the development of ligands for
the separation of actinides from lanthanides contained in nuclear waste streams in the …

[PDF][PDF] Rare earth elements removal techniques from water/wastewater: A review

O Pereao, C Bode-Aluko, O Fatoba… - Desalin. Water …, 2018 - academia.edu
abstract The rare-earth elements (REEs) remain very important due to the growing increase
in their demand and for their critical and indispensable use in many high-tech industries …

Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf2N]: A New Approach to Spent Nuclear Fuel Recycling

FL Fan, Z Qin, SW Cao, CM Tan, QG Huang… - Inorganic …, 2018 - ACS Publications
Here, we propose the use of carboxyl-functionalized ionic liquid,[Hbet][Tf2N], to separate the
fission products from spent nuclear fuels. This innovative method allows the selective …

Origin of selectivity of a triazinyl ligand for americium (III) over neodymium (III)

D Dan, C Celis‐Barros, FD White… - … A European Journal, 2019 - Wiley Online Library
Abstract [M (EtBTP) 3][BPh4] 3⋅ 3 CH3CN (M= Nd, Am; EtBTP= 2, 6‐bis (5, 6‐diethyl‐1, 2, 4‐
triazin‐3‐yl) pyridine) have been synthesized from reactions of MCl3⋅ n H2O with EtBTP in …

Insights into the Extraction of Actinides from Lanthanides Using 3, 3'‐Dimethoxy‐phenyl‐bis‐1, 2, 4‐triazinyl‐2, 6‐pyridine Ligand–A DFT Study

C Ebenezer, RV Solomon - ChemistrySelect, 2020 - Wiley Online Library
Abstract Recently reported 3, 3'‐dimethoxy‐phenyl‐bis‐1, 2, 4‐triazinyl‐2, 6‐pyridine
(DMOP‐BTP) ligand is recognized as an efficient candidate for the stripping of actinides (An) …

Screening of the Structure of Americium Extractants Based on a 2, 2'‐Bipyridyl Scaffold: a Simple Way to a N2, O2‐Tetradentate Ligands Library for Rational Design of …

NE Borisova, AV Ivanov, PI Matveev… - …, 2018 - Wiley Online Library
A library of N‐ethylanilides of 2, 2′‐bipyridine‐6, 6′‐dicarboxylic acids were synthesized
to evaluate the influence of the side chains on the extraction properties. The structure of the …