The precise construction of chiral molecules is a core research area in chemical science and
technology. Among the plethora of reported synthetic methods, asymmetric catalysis has …

Although the high efficiency of the homogeneous processes, using rhodium or iridium
complexes, was clearly demonstrated industrially, heterogeneous catalysts offer the …

In the past few decades, the advances of CO2 reduction have been mostly focused on the
synthesis of C1 products, such as CO, formic acid, methanol, and methane. However, the …

In the last decade there have been numerous advances in the area of rhodium-catalyzed
hydroformylation, such as highly selective catalysts of industrial importance, new insights …

Conspectus While spectacular successes have been achieved in homogeneous catalysis
with the use of achiral diphosphine ligands featuring a wide natural bite angle, such as …

Recently, the chemistry of chiral aromatic spiroketals has received much attention because
they are key substructures in biologically active natural products,[1] pharmaceuticals,[2] and …

Showing a backbone: The spiroketal backbone of the bis (phosphine) ligand 1 led to good
regio‐and enantioselectivity in the palladium‐catalyzed asymmetric allylic amination of …

This review highlights the use of a bisphosphine ligand group in homogeneous catalysis.
This ligand group is known as the Xantphos-like ligands, which are based on the generic …

Exceptionally high activity (with a TON up to 4750) of the palladium complexes of SKP
ligand was discovered in the catalysis of asymmetric allylic amination of MBH adducts with …

The enantioselective tandem reaction of β, γ‐unsaturated α‐ketoesters with β‐alkynyl
ketones was realized by a bimetallic catalytic system of achiral AuΙΙΙ salt and chiral N, N …