Controlled ring-opening polymerization of lactide and glycolide

O Dechy-Cabaret, B Martin-Vaca… - Chemical reviews, 2004 - ACS Publications
Synthetic petrochemical-based polymers have had a tremendous industrial impact since the
1940s. Despite the numerous advantages of these materials, two major drawbacks remain …

Biocompatible initiators for lactide polymerization

RH Platel, LM Hodgson, CK Williams - Polymer Reviews, 2008 - Taylor & Francis
The review summarizes recent developments in the preparation and use of new initiators for
the ring opening polymerization of lactide. The review compares different classes of initiator …

Stereochemistry of lactide polymerization with chiral catalysts: new opportunities for stereocontrol using polymer exchange mechanisms

TM Ovitt, GW Coates - Journal of the American Chemical Society, 2002 - ACS Publications
The synthesis of chiral aluminum and yttrium alkoxides and their application for lactide
polymerization are reported. The complexes (SalBinap) MOR [4, M= Al, R= iPr; 5, M= Y …

Recent developments in main group metal complexes catalyzed/initiated polymerization of lactides and related cyclic esters

J Wu, TL Yu, CT Chen, CC Lin - Coordination Chemistry Reviews, 2006 - Elsevier
This review describes recent development of ring-opening polymerization of lactides and
related cyclic esters using main group metal complexes as catalysts/initiators. The …

MALDI time‐of‐flight mass spectrometry of synthetic polymers

MWF Nielen - Mass Spectrometry Reviews, 1999 - Wiley Online Library
Mass spectrometry of intact synthetic polymers has been limited to field desorption (FD) MS
for many years. More recently, soft ionization techniques such as electrospray (ESI) and …

[图书][B] Controlled ring-opening polymerization: polymers with designed macromolecular architecture

KM Stridsberg, M Ryner, AC Albertsson - 2002 - Springer
This paper reviews ring-opening polymerization of lactones and lactides with different types
of initiators and catalysts as well as their use in the synthesis of macromolecules with …

Controlled and stereoselective polymerization of lactide: Kinetics, selectivity, and microstructures

Z Zhong, PJ Dijkstra, J Feijen - Journal of the American Chemical …, 2003 - ACS Publications
Chiral aluminum isopropoxides based on enantiopure or racemic cyclohexylsalen ligand
(Jacobsen ligand) have been prepared and employed for stereoelective/stereoselective ring …

Polymerization of lactide and related cyclic esters by discrete metal complexes

BJ O'Keefe, MA Hillmyer, WB Tolman - Journal of the Chemical Society …, 2001 - pubs.rsc.org
This perspective highlights recent research on the preparation of polyesters by the ring-
opening polymerization of cyclic esters employing well-characterized metal complexes …

[(salen) Al]-mediated, controlled and stereoselective ring-opening polymerization of lactide in solution and without solvent: synthesis of highly isotactic polylactide …

Z Zhong, PJ Dijkstra, J Feijen - … Chemie (international edition), 2002 - research.utwente.nl
Abstract Easily accessible [(salen)(iPrO) Al] exerts excellent molecular-weight and
stereochemical control in lactide polymerization either in solution or in the absence of …

Mechanism of cyclic ester polymerization initiated with Tin (II) Octoate. 2. Macromolecules fitted with Tin (II) alkoxide species observed directly in MALDI− TOF Spectra

A Kowalski, A Duda, S Penczek - Macromolecules, 2000 - ACS Publications
Polymerization of ε-caprolactone (CL) initiated with tin (II) octoate (tin (II) 2-
ethylhexanoate,(Sn (Oct) 2)) in the presence of butyl alcohol (BuOH) or water and conducted …