Colloidal synthesis of metal nanocrystals: from asymmetrical growth to symmetry breaking

QN Nguyen, C Wang, Y Shang, A Janssen… - Chemical …, 2022 - ACS Publications
Nanocrystals offer a unique platform for tailoring the physicochemical properties of solid
materials to enhance their performances in various applications. While most work on …

Bimetallic nanocrystals: syntheses, properties, and applications

KD Gilroy, A Ruditskiy, HC Peng, D Qin, Y Xia - Chemical reviews, 2016 - ACS Publications
Achieving mastery over the synthesis of metal nanocrystals has emerged as one of the
foremost scientific endeavors in recent years. This intense interest stems from the fact that …

Carbon-supported Pt-based alloy electrocatalysts for the oxygen reduction reaction in polymer electrolyte membrane fuel cells: particle size, shape, and composition …

YJ Wang, N Zhao, B Fang, H Li, XT Bi… - Chemical reviews, 2015 - ACS Publications
Global energy demands are projected to grow 36% over the current level by the year 2030.
1 Polymer electrolyte membrane fuel cells (PEMFCs) are among the most promising …

Shape‐controlled synthesis of metal nanocrystals: simple chemistry meets complex physics?

Y Xia, Y Xiong, B Lim… - Angewandte Chemie …, 2009 - Wiley Online Library
Nanocrystals are fundamental to modern science and technology. Mastery over the shape of
a nanocrystal enables control of its properties and enhancement of its usefulness for a given …

Icosahedral platinum alloy nanocrystals with enhanced electrocatalytic activities

J Wu, L Qi, H You, A Gross, J Li… - Journal of the American …, 2012 - ACS Publications
This communication describes the synthesis of Pt–M (M= Au, Ni, Pd) icosahedral
nanocrystals based on the gas reducing agent in liquid solution method. Both CO gas and …

Relativistic effects in chemistry: more common than you thought

P Pyykkö - Annual review of physical chemistry, 2012 - annualreviews.org
Relativistic effects can strongly influence the chemical and physical properties of heavy
elements and their compounds. This influence has been noted in inorganic chemistry …

Structural properties of nanoclusters: Energetic, thermodynamic, and kinetic effects

F Baletto, R Ferrando - Reviews of modern physics, 2005 - APS
The structural properties of free nanoclusters are reviewed. Special attention is paid to the
interplay of energetic, thermodynamic, and kinetic factors in the explanation of cluster …

Aromatic thiolate-protected series of gold nanomolecules and a contrary structural trend in size evolution

NA Sakthivel, A Dass - Accounts of chemical research, 2018 - ACS Publications
Conspectus Thiolate-protected gold nanoparticles (AuNPs) are a special class of
nanomaterials that form atomically precise NPs with distinct numbers of Au atoms (n) and …

The effect of size-dependent nanoparticle energetics on catalyst sintering

CT Campbell, SC Parker, DE Starr - Science, 2002 - science.org
Calorimetric measurements of metal adsorption energies directly provide the energies of
metal atoms in supported metal nanoparticles. As the metal coverage increases, the …

Shape-control and electrocatalytic activity-enhancement of Pt-based bimetallic nanocrystals

NS Porter, H Wu, Z Quan, J Fang - Accounts of chemical research, 2013 - ACS Publications
Due to the increasing worldwide energy demand and environ-mental concerns, the need for
alternative energy sources is growing stronger, and platinum catalysts in fuel cells may help …