Organic radicals with inversion of SOMO and HOMO energies and potential applications in optoelectronics

S Kasemthaveechok, L Abella, J Crassous… - Chemical …, 2022 - pubs.rsc.org
Organic radicals possessing an electronic configuration in which the energy of the singly
occupied molecular orbital (SOMO) is below the highest doubly occupied molecular orbital …

Achiral-Core-Metal Change in Isomorphic Enantiomeric Ag12Ag32 and Au12Ag32 Clusters Triggers Circularly Polarized Phosphorescence

YJ Kong, JH Hu, XY Dong, Y Si, ZY Wang… - Journal of the …, 2022 - ACS Publications
Understanding how the chiral or achiral section in chiral nanostructures contributes to
circularly polarized light emission (CPLE) at the atomic level is of fundamental importance …

Atomically precise chiral metal nanoclusters for circularly polarized light detection

WM He, J Zha, Z Zhou, YJ Cui, P Luo, L Ma… - Angewandte …, 2024 - Wiley Online Library
Circularly polarized light (CPL) detection is of great significance in various applications such
as drug identification, sensing and imaging. Atomically precise chiral metal nanoclusters …

Flow-induced periodic chiral structures in an achiral nematic liquid crystal

Q Zhang, W Wang, S Zhou, R Zhang… - Nature …, 2024 - nature.com
Supramolecular chirality typically originates from either chiral molecular building blocks or
external chiral stimuli. Generating chirality in achiral systems in the absence of a chiral input …

Searching for ultralight axions with twisted cavity resonators of anyon rotational symmetry with bulk modes of nonzero helicity

JF Bourhill, ECI Paterson, M Goryachev, ME Tobar - Physical Review D, 2023 - APS
Möbius-ring resonators stem from a well-studied and fascinating geometrical structure which
features a one-sided topology, the Möbius strip, and have been shown to exhibit fermion …

Enigma of Pyramidal Neurons: Chirality-Centric View on Biological Evolution. Congruence to Molecular, Cellular, Physiological, Cognitive, and Psychological …

VV Dyakin, NV Dyakina-Fagnano - Symmetry, 2024 - mdpi.com
The mechanism of brain information processing unfolds within spatial and temporal domains
inherently linked to the concept of space–time symmetry. Biological evolution, beginning …

Tailoring the Performance of 19F-Labeled Probes via Dynamic Covalent Chemistry for Improved Chiral Discrimination

J Weng, L Wen, G Gu, W Bao, J Wu, Y Zhao - Analytical Chemistry, 2024 - ACS Publications
This work presents a novel strategy for postmodifying probes using dynamic covalent
chemistry. Leveraging reversible interactions between boronic acid and diols, we obtained a …

Effects of shape and solute-solvent compatibility on the efficacy of chirality transfer: Nanoshapes in nematics

A Nemati, L Querciagrossa, C Callison, S Shadpour… - Science …, 2022 - science.org
Chirality, as a concept, is well understood at most length scales. However, quantitative
models predicting the efficacy of the transmission of chirality across length scales are …

SMG-BERT: integrating stereoscopic information and chemical representation for molecular property prediction

J Zhang, W Du, X Yang, D Wu, J Li, K Wang… - Frontiers in Molecular …, 2023 - frontiersin.org
Molecular property prediction is a crucial task in various fields and has recently garnered
significant attention. To achieve accurate and fast prediction of molecular properties …

The switchable chirality and optical properties of hexabenzo [a, c, k, m, u, w] trinaphthylene controlled by synergistic effect of static electric field and substituents: A DFT …

FY Zhang, XQ Han, YJ Zhang, HL Xu, ZM Su - Dyes and Pigments, 2024 - Elsevier
This work selected the planar molecule hexabenzo [a, c, k, m, u, w] trinaphthylene (HBTN)
with electron donor and acceptor, and introduced static electric field perpendicular to the …