Electrochemistry of metal-metal bonded diruthenium complexes

E Van Caemelbecke, T Phan, WR Osterloh… - Coordination Chemistry …, 2021 - Elsevier
This review summarizes the known electrochemistry of metal-metal bonded diruthenium
complexes containing an air-stable Ru 2 4+, Ru 2 5+ or Ru 2 6+ core or an in-situ generated …

Electrostatic interactions within mixed-valent compounds

A Hildebrandt, D Miesel, H Lang - Coordination Chemistry Reviews, 2018 - Elsevier
The electrochemical properties of bi-and multi-metallic compounds are a convolution of
several factors, among which through-bond electron transfer and through-space electrostatic …

(Multi) ferrocenyl five-membered heterocycles: excellent connecting units for electron transfer studies

A Hildebrandt, H Lang - Organometallics, 2013 - ACS Publications
The electro-and spectroelectrochemical behavior of diverse (multi) ferrocenyl five-
membered heterocyclic compounds, including furan, thiophene, pyrroles, phospholes, etc. is …

Cyclic Voltammetric Study of 2‐Hydroxybenzophenone (HBP) Derivatives and the Correspondent Change in the Orbital Energy Levels in Different Solvents

AA Adeniyi, TL Ngake, J Conradie - Electroanalysis, 2020 - Wiley Online Library
The experimental UV and CV of five substituted 2‐hydroxybenzophenones in solvents
acetonitrile, n‐dimethylformamide and dimethylsulfoxide are presented. Results obtained …

Electronically intercommunicating iron centers in di-and tetraferrocenyl pyrroles

A Hildebrandt, D Schaarschmidt, H Lang - Organometallics, 2011 - ACS Publications
Novel 2, 5-diferrocenyl-1-phenyl-1 H-pyrrole (4) and 2, 3, 4, 5-tetraferrocenyl-1-phenyl-1 H-
pyrrole (6) have been prepared by a 2-or 4-fold Negishi cross-coupling reaction of 2, 5 …

A star-shaped supercrowded 2, 3, 4, 5-tetraferrocenylthiophene: synthesis, solid-state structure, and electrochemistry

A Hildebrandt, T Rüffer, E Erasmus, JC Swarts… - …, 2010 - ACS Publications
Supercrowded 2, 3, 4, 5-tetraferrocenylthiophene (4) has been synthesized by a fourfold
Negishi ferrocenylation of tetrabromothiophene (3) with FcZnCl (2)(Fc=(η5-C5H4)(η5-C5H5) …

Electronic coupling in 1, 2, 3-triazole bridged ferrocenes and its impact on reactive oxygen species generation and deleterious activity in cancer cells

P Biegański, E Kovalski, N Israel, E Dmitrieva… - Inorganic …, 2022 - ACS Publications
Mixed-valence (MV) binuclear ferrocenyl compounds have long been studied as models for
testing theories of electron transfer and in attempts to design molecular-scale electronic …

Influence of electron delocalization in heterocyclic core systems on the electrochemical communication in 2, 5-Di-and 2, 3, 4, 5-Tetraferrocenyl thiophenes, furans, and …

A Hildebrandt, D Schaarschmidt, R Claus… - Inorganic …, 2011 - ACS Publications
A series of 2, 5-di-and 2, 3, 4, 5-tetraferrocenyl-substituted thiophenes, furans, and pyrroles
were synthesized using the Negishi C, C cross-coupling protocol. The electronic and …

Di-and triferrocenyl (hetero) aromatics: Synthesis, characterization,(spectro-) electrochemistry, and calculations

U Pfaff, A Hildebrandt, D Schaarschmidt, T Hahn… - …, 2012 - ACS Publications
A series of di-and triferrocenyl (hetero) aromatics including 2, 5-diferrocenylpyridine (4), 2, 6-
diferrocenylpyridine (5), 1, 3, 5-triferrocenylbenzene (9), 2, 4, 6-triferrocenylpyridine (10) …

Electron transfer studies on ferrocenylthiophenes: synthesis, properties, and electrochemistry

JM Speck, R Claus, A Hildebrandt, T Rüffer… - …, 2012 - ACS Publications
The ferrocenylthiophenes 2, 3-Fc2-c C4H2S (9), 2, 4-Fc2-c C4H2S (10), and 2, 3, 4-Fc3-c
C4HS (11) have been prepared by a 2-or 3-fold Negishi cross-coupling reaction of the …