The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

The development of novel and efficient earth-abundant metal catalysts as inexpensive and
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …

Our planet urgently needs sustainable solutions to alleviate the anthropogenic global
warming and climate change. Homogeneous catalysis has the potential to play a …

Catalytic hydrogen transfer reactions have enormous academic and industrial applications
for the production of diverse molecular scaffolds. Over the past few decades, precious late …

Both imidazol-2-ylidene (ImNHC) and 1, 2, 3-triazol-5-ylidene (tzNHC) have evolved to be
elite groups of N-heterocyclic carbene (NHC) ligands for homogeneous catalysis. To …

Direct synthesis of N-heterocycles via the acceptorless dehydrogenative coupling is very
challenging and scarcely reported under 3d transition-metal catalysis. Here, we have …

We report a sustainable and eco-friendly approach for selective N-alkylation of various
amines by alcohols, catalyzed by a well-defined Zn (II)-catalyst, Zn (La) Cl2 (1a), bearing a …

The application of nontoxic, earth-abundant transition metals in place of costly noble metals
is a paramount goal in catalysis and is especially interesting if the air-and moisture-stable …

The development of sustainable catalytic protocols that circumvent the use of expensive and
precious metal catalysts and avoid toxic reagents plays a crucial role in organic synthesis …

A highly active Mn (I) catalyst based on a nonsymmetric PN3-ligand scaffold for the N-
alkylation of amines with alcohols utilizing the borrowing hydrogen methodology is reported …