Chemicals from alkynes with palladium catalysts

R Chinchilla, C Najera - Chemical reviews, 2014 - ACS Publications
The carbon− carbon triple bond of alkynes is one of the basic functional groups, its reactions
belonging to the foundations of organic chemistry. In the past decades, acetylene chemistry …

Transition‐Metal‐Catalyzed Utilization of Methanol as a C1 Source in Organic Synthesis

K Natte, H Neumann, M Beller… - Angewandte Chemie …, 2017 - Wiley Online Library
Methanol is used as a common solvent, cost‐effective reagent, and sustainable feedstock for
value‐added chemicals, pharmaceuticals, and materials. Among the various applications …

[图书][B] Applied homogeneous catalysis with organometallic compounds: a comprehensive handbook in four volumes

B Cornils, WA Herrmann, M Beller, R Paciello - 2017 - books.google.com
The completely revised third edition of this four-volume classic is fully updated and now
includes such topics as as CH-activation and multicomponent reactions. It describes the …

Palladium‐catalyzed oxidative carbonylation reactions

XF Wu, H Neumann, M Beller - ChemSusChem, 2013 - Wiley Online Library
Palladium‐catalyzed coupling reactions have become a powerful tool for advanced organic
synthesis. This type of reaction is of significant value for the preparation of pharmaceuticals …

[PDF][PDF] Oxidative carbonylation as a powerful tool for the direct synthesis of carbonylated heterocycles

B Gabriele, R Mancuso, G Salerno - European Journal of Organic …, 2012 - academia.edu
Carbonylation, the incorporation of carbon monoxide into an organic substrate, is now
widely recognized as a very important tool in industrial and organic chemistry.[1, 2] It allows …

Gold-catalyzed regioselective hydration of propargyl acetates assisted by a neighboring carbonyl group: access to α-acyloxy methyl ketones and synthesis of (±) …

N Ghosh, S Nayak, AK Sahoo - The Journal of organic chemistry, 2011 - ACS Publications
A general atom-economical approach for the synthesis of α-acyloxy methyl ketone is
demonstrated through regioselective hydration of a wide range of propargyl acetates …

Gold-catalyzed intermolecular hydrophenoxylation of unactivated internal alkynes

MR Kuram, M Bhanuchandra… - The Journal of Organic …, 2010 - ACS Publications
A general and simple strategy for the synthesis of functionally diverse arylvinyl ethers is
reported through gold-catalyzed intermolecular addition of electronically and sterically …

Co-catalysis over a bi-functional ligand-based Pd-catalyst for tandem bis-alkoxycarbonylation of terminal alkynes

D Yang, H Liu, DL Wang, Z Luo, Y Lu, F Xia, Y Liu - Green Chemistry, 2018 - pubs.rsc.org
A bi-functional ligand (L1) containing a diphosphino fragment and sulfonic acid group (–
SO3H) enabled PdCl2 (MeCN) 2 to efficiently catalyze the tandem bis-alkoxycarbonylation …

Metal-catalyzed carbonylation of alkynes: key aspects and recent development

S Quintero-Duque, KM Dyballa, I Fleischer - Tetrahedron Letters, 2015 - Elsevier
Carbonyl compounds represent an important class of synthetic intermediates in organic
chemistry with growing industrial significance. Among the plethora of methods available for …

The use of 2-(1-alkoxyalkylidene)-1, 3-dicarbonyl compounds in organic synthesis

YS Kudyakova, DN Bazhin, MV Goryaeva… - Russian Chemical …, 2014 - iopscience.iop.org
The review focuses on the methods of synthesis of 2-(1-alkoxyalkylidene)-1, 3-dicarbonyl
compounds and their chemical transformations. The reactivity of such compounds toward …