Reactivity of acyclic diaminocarbene ligands
MA Kinzhalov, KV Luzyanin - Coordination Chemistry Reviews, 2019 - Elsevier
Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in
organometallic chemistry, catalysis, photophysics and crystal engineering. Although the …
organometallic chemistry, catalysis, photophysics and crystal engineering. Although the …
Difference in Energy between Two Distinct Types of Chalcogen Bonds Drives Regioisomerization of Binuclear (Diaminocarbene)PdII Complexes
The reaction of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with various 1, 3-thiazol-and 1, 3,
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
H2C(X)–X···X– (X = Cl, Br) Halogen Bonding of Dihalomethanes
The dihalomethane–halide H2C (X)–X··· X–(X= Cl, Br) halogen bonding was detected in a
series of the cis-[PdX (CNCy){C (NHCy) NHC6H2Me2 N H2}] X• CH2X2 (X= Cl, Br) …
series of the cis-[PdX (CNCy){C (NHCy) NHC6H2Me2 N H2}] X• CH2X2 (X= Cl, Br) …
Luminescent cyclometalated platinum (II) complexes with acyclic diaminocarbene ligands: structural, photophysical and biological properties
Four new cyclometalated Pt (II) complexes bearing acyclic diaminocarbene (ADC)
ligands,[Pt (C^ N) Cl {C (NHXyl)(NHR)}][C^ N= 2, 6-difluorophenylpyridine (dfppy) …
ligands,[Pt (C^ N) Cl {C (NHXyl)(NHR)}][C^ N= 2, 6-difluorophenylpyridine (dfppy) …
Ligation-enhanced π-hole··· π interactions involving isocyanides: Effect of π-hole··· π noncovalent bonding on conformational stabilization of acyclic diaminocarbene …
The reaction of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with the aminoazoles [1 H-
imidazol-2-amine (1), 4 H-1, 2, 4-triazol-3-amine (2), 1 H-tetrazol-5-amine (3), 1 H …
imidazol-2-amine (1), 4 H-1, 2, 4-triazol-3-amine (2), 1 H-tetrazol-5-amine (3), 1 H …
Phosphorescent iridium (III) complexes with acyclic diaminocarbene ligands as chemosensors for mercury
AA Eremina, MA Kinzhalov, EA Katlenok… - Inorganic …, 2020 - ACS Publications
A new application for bis (cyclometalated) iridium (III) species containing ancillary acyclic
diaminocarbene ligands, viz. for sensing of mercury (II) ions, is disclosed. A family of bis …
diaminocarbene ligands, viz. for sensing of mercury (II) ions, is disclosed. A family of bis …
Synthesis and contemporary applications of platinum group metals complexes with acyclic diaminocarbene ligands
MA Kinzhalov, KV Luzyanin - Russian Journal of Inorganic Chemistry, 2022 - Springer
Complexes of platinum group metals with acyclic diaminocarbene ligands have found
application as transition metal catalysts, photoluminescent materials, chemosensors, and …
application as transition metal catalysts, photoluminescent materials, chemosensors, and …
Experimental and computational tuning of metalla-N-heterocyclic carbenes at palladium (ii) and platinum (ii) centers
MV Kashina, KV Luzyanin, EA Katlenok… - Dalton …, 2022 - pubs.rsc.org
Palladium (II) and platinum (II) complexes featuring metalla-N-heterocyclic carbenes (7–12)
were synthesised via metal-mediated coupling between equimolar cis-[MCl2 (CNR) 2](R= 2 …
were synthesised via metal-mediated coupling between equimolar cis-[MCl2 (CNR) 2](R= 2 …
Intra-/Intermolecular Bifurcated Chalcogen Bonding in Crystal Structure of Thiazole/Thiadiazole Derived Binuclear (Diaminocarbene)PdII Complexes
The coupling of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with 4-phenylthiazol-2-amine in
molar ratio 2: 3 at RT in CH2Cl2 leads to binuclear (diaminocarbene) PdII complex 3c. The …
molar ratio 2: 3 at RT in CH2Cl2 leads to binuclear (diaminocarbene) PdII complex 3c. The …
Halides Held by Bifurcated Chalcogen–Hydrogen Bonds. Effect of μ(S,N–H)Cl Contacts on Dimerization of Cl(carbene)PdII Species
The reaction of cis-[PdCl2 (CNCy) 2](1) with thiazol-2-amines (2–10) leads to the C, N-
chelated diaminocarbene-like complexes [PdCl {C (N (H) 4, 5-R2-thiazol-2-yl) …
chelated diaminocarbene-like complexes [PdCl {C (N (H) 4, 5-R2-thiazol-2-yl) …