Low-temperature gas-phase formation of indene in the interstellar medium
Polycyclic aromatic hydrocarbons (PAHs) are fundamental molecular building blocks of
fullerenes and carbonaceous nanostructures in the interstellar medium and in combustion …
fullerenes and carbonaceous nanostructures in the interstellar medium and in combustion …
Breaking Strong Alkynyl-Phenyl Bonds: Poly(para-phenylene ethynylene)s under Mechanical Stress
Stronger chemical bonds withstand higher mechanical forces; thus, the rupture of single
bonds is preferred over the rupture of double or triple bonds or aromatic rings. We …
bonds is preferred over the rupture of double or triple bonds or aromatic rings. We …
A chemical dynamics study of the reaction of the methylidyne radical (CH, X 2 Π) with dimethylacetylene (CH 3 CCCH 3, X 1 A 1g)
The gas-phase reaction of the methylidyne (CH; X2Π) radical with dimethylacetylene
(CH3CCCH3; X1A1g) was studied at a collision energy of 20.6 kJ mol− 1 under single …
(CH3CCCH3; X1A1g) was studied at a collision energy of 20.6 kJ mol− 1 under single …
A chemical dynamics study on the gas-phase formation of triplet and singlet C5H2 carbenes
Since the postulation of carbenes by Buchner (1903) and Staudinger (1912) as electron-
deficient transient species carrying a divalent carbon atom, carbenes have emerged as key …
deficient transient species carrying a divalent carbon atom, carbenes have emerged as key …
Spiers Memorial Lecture: New directions in molecular scattering
The field of Molecular Scattering is reviewed as it pertains to gas-gas as well as gas-surface
chemical reaction dynamics. We emphasize the importance of collaboration of experiment …
chemical reaction dynamics. We emphasize the importance of collaboration of experiment …
Low-temperature gas-phase formation of cyclopentadiene and its role in the formation of aromatics in the interstellar medium
Z Yang, IA Medvedkov, SJ Goettl, AA Nikolayev… - Proceedings of the …, 2024 - pnas.org
The cyclopentadiene (C5H6) molecule has emerged as a molecular building block of
nonplanar polycyclic aromatic hydrocarbons (PAHs) and carbonaceous nanostructures such …
nonplanar polycyclic aromatic hydrocarbons (PAHs) and carbonaceous nanostructures such …
Gas-Phase Formation of 1,3,5,7-Cyclooctatetraene (C8H8) through Ring Expansion via the Aromatic 1,3,5-Cyclooctatrien-7-yl Radical (C8H9•) Transient
Gas-phase 1, 3, 5, 7-cyclooctatetraene (C8H8) and triplet aromatic 1, 3, 5, 7-
cyclooctatetraene (C8H8) were formed for the first time through bimolecular methylidyne …
cyclooctatetraene (C8H8) were formed for the first time through bimolecular methylidyne …
Exploring the Chemical Dynamics of Phenylethynyl Radical (C6H5CC; X2A1) Reactions with Allene (H2CCCH2; X1A1) and Methylacetylene (CH3CCH; X1A1)
SJ Goettl, Z Yang, S Kollotzek, D Paul… - The Journal of …, 2023 - ACS Publications
The bimolecular gas-phase reactions of the phenylethynyl radical (C6H5CC, X2A1) with
allene (H2CCCH2), allene-d 4 (D2CCCD2), and methylacetylene (CH3CCH) were studied …
allene (H2CCCH2), allene-d 4 (D2CCCD2), and methylacetylene (CH3CCH) were studied …
Directed Gas‐Phase Synthesis of Triafulvene under Single‐Collision Conditions
The triafulvene molecule (c‐C4H4)—the simplest representative of the fulvene family—has
been synthesized for the first time in the gas phase through the reaction of the methylidyne …
been synthesized for the first time in the gas phase through the reaction of the methylidyne …
Directed gas phase preparation of ethynylallene (H 2 CCCHCCH; X 1 A′) via the crossed molecular beam reaction of the methylidyne radical (CH; X 2 Π) with …
The gas-phase bimolecular reaction of the methylidyne (CH; X2Π) radical with
vinylacetylene (H2CCHCCH; X1A′) was conducted at a collision energy of 20.3 kJ mol− 1 …
vinylacetylene (H2CCHCCH; X1A′) was conducted at a collision energy of 20.3 kJ mol− 1 …