Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond

X Liu, C Xu, M Wang, Q Liu - Chemical reviews, 2015 - ACS Publications
Method B 692 3.7. Selective Trifluoromethylation of Multi-Functional Substrates 693 3.8.
Enantioselective Trifluoromethylation 695 3.8. 1. Aldehydes and Ketones: With Cinchona …

Contemporary carbocation chemistry: applications in organic synthesis

RR Naredla, DA Klumpp - Chemical reviews, 2013 - ACS Publications
Contemporary Carbocation Chemistry: Applications in Organic Synthesis | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews …

Cobalt-electrocatalytic C–H hydroxyalkylation of N-heteroarenes with trifluoromethyl ketones

T He, C Liang, S Huang - Chemical Science, 2023 - pubs.rsc.org
Trifluoromethyl carbinols and N-heteroarenes are both prevalent in bioactive molecules.
However, access to high-value pharmacophores combining these two functional groups still …

Trifluoromethyl ketones: properties, preparation, and application

CB Kelly, MA Mercadante… - Chemical Communications, 2013 - pubs.rsc.org
Trifluoromethyl ketones (TFMKs) are exceedingly valuable synthetic targets in their own right
and as synthons in the construction of fluorinated pharmacons. This Feature Article provides …

Degradation of bisphenol A, bisphenol S, and bisphenol AF in the UV-LED/chlorine reaction: Effect of pH on the kinetics, transformation products, and degradation …

J Lee, S Eom, S Sohn, T Kim, KD Zoh - Chemical Engineering Journal, 2023 - Elsevier
We investigated the UV-LED/chlorine reaction for the degradation of bisphenol A (BPA) and
its alternatives, bisphenol S (BPS) and bisphenol AF (BPAF) in water. Three bisphenols …

Novel high molecular weight aromatic fluorinated polymers from one-pot, metal-free step polymerizations

LI Olvera, MT Guzmán-Gutiérrez, MG Zolotukhin… - …, 2013 - ACS Publications
A novel series of linear, high-molecular-weight polymers and copolymers was synthesized
by one-pot, metal-free superacid-catalyzed reaction of trifluoromethylalkyl (1 a–1c) and …

Catalytic asymmetric synthesis of CF 3-substituted tertiary propargylic alcohols via direct aldol reaction of α-N 3 amide

H Noda, F Amemiya, K Weidner, N Kumagai… - Chemical …, 2017 - pubs.rsc.org
Organofluorine compounds are found in several important classes of chemicals, such as
pharmaceuticals, agrochemicals, and functional materials. Chemists have been immensely …

Surface-Modified S═O Microenvironment Boosts Catalyzed Oxidation of Alcohol via Hydrogen Bond Interactions

X Feng, S Shi, G Zhu, Y Wang, J Cao, J Xu - ACS Catalysis, 2024 - ACS Publications
Enzymes have unique structures, with various amino acid residues encapsulating metal
active sites. Their high performance is mainly achieved via weak interactions between the …

Neutral Five‐Coordinate Arylated Copper (III) Complex: Key Intermediate in Copper‐Mediated Arene Trifluoromethylation

G Wang, M Li, X Leng, X Xue… - Chinese Journal of …, 2022 - Wiley Online Library
Comprehensive Summary Five‐coordinate neutral Cu (III) complexes have long been
considered as the key intermediates in copper‐mediated/catalyzed arene …

Transition-metal-free trifluoromethylative difunctionalization of olefins and alkynes: approaches and challenges ahead

K Keerthika, S Nath, K Geetharani - Catalysis Science & Technology, 2020 - pubs.rsc.org
Strategies for the introduction of the trifluoromethyl group in organic molecules have been
extensively explored in the past. Trifluoromethylative difunctionalization of carbon–carbon …