Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies

S Chen, X Chang, G Sun, T Zhang, Y Xu… - Chemical SOCIETY …, 2021 - pubs.rsc.org
Propylene is an important building block for enormous petrochemicals including
polypropylene, propylene oxide, acrylonitrile and so forth. Propane dehydrogenation (PDH) …

Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation

Y Zhou, F Wei, H Qi, Y Chai, L Cao, J Lin, Q Wan… - Nature Catalysis, 2022 - nature.com
Single-atom catalysts with uniform metal active sites show potential for selectivity control.
However, their application to high-temperature propane dehydrogenation remains …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation

G Sun, ZJ Zhao, R Mu, S Zha, L Li, S Chen… - Nature …, 2018 - nature.com
Noble-metal alloys are widely used as heterogeneous catalysts. However, due to the
existence of scaling properties of adsorption energies on transition metal surfaces, the …

Dehydrogenation of light alkanes to mono-olefins

C Li, G Wang - Chemical Society Reviews, 2021 - pubs.rsc.org
In the past several decades, light alkane dehydrogenation to mono-olefins, especially
propane dehydrogenation to propylene has gained widespread attention and much …

Aromatics production via methanol-mediated transformation routes

T Li, T Shoinkhorova, J Gascon, J Ruiz-Martinez - ACS Catalysis, 2021 - ACS Publications
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …

Direct and oxidative dehydrogenation of propane: from catalyst design to industrial application

JH Carter, T Bere, JR Pitchers, DG Hewes… - Green …, 2021 - pubs.rsc.org
The direct formation of propene from propane is a well-established commercial process,
which on the basis of energy consumption, is environmentally preferred to the current large …

The comparison between single atom catalysis and surface organometallic catalysis

MK Samantaray, V D'Elia, E Pump, L Falivene… - Chemical …, 2019 - ACS Publications
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …

Propane dehydrogenation on single-site [PtZn4] intermetallic catalysts

S Chen, ZJ Zhao, R Mu, X Chang, J Luo, SC Purdy… - Chem, 2021 - cell.com
Propane dehydrogenation (PDH) is a commercial propylene production technology that has
received much attention, but high reaction temperatures result in a decrease of propylene …