Heterometallic 3d–4f Complexes as Single‐Molecule Magnets

A Dey, J Acharya… - Chemistry–An Asian …, 2019 - Wiley Online Library
Heterometallic 3d‐4f complexes are being investigated, for some time, as being useful in
molecular magnetism, particularly as single‐molecule magnets (SMMs). This interest is …

Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Magnetic materials based on heterometallic Cr II/III–Ln III complexes

P Shukla, S Das, P Bag, A Dey - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Accommodating disparate spin centres within a single ensemble is a valuable synthetic
strategy to obtain interesting molecular magnetic materials. 3d–4f heterometallic complexes …

Heterometallic 3d–4f single molecule magnets containing diamagnetic metal ions

A Chakraborty, J Goura, P Kalita, A Swain… - Dalton …, 2018 - pubs.rsc.org
Molecular nano magnets such as single-molecule magnets (SMMs) are a class of
coordination complexes with numerous potential applications such as information storage …

Effect of Ligand Substitution around the DyIII on the SMM Properties of Dual-Luminescent Zn–Dy and Zn–Dy–Zn Complexes with Large Anisotropy Energy Barriers: A …

JP Costes, S Titos-Padilla, I Oyarzabal… - Inorganic …, 2016 - ACS Publications
The new dinuclear ZnII–DyIII and trinuclear ZnII–DyIII-ZnII complexes of formula [(LZnBrDy
(ovan)(NO3)(H2O)](H2O)· 0.5 (MeOH)(1) and [(L1ZnBr) 2Dy (MeOH) 2](ClO4)(3)(L and L1 …

Modelling spin Hamiltonian parameters of molecular nanomagnets

T Gupta, G Rajaraman - Chemical Communications, 2016 - pubs.rsc.org
Molecular nanomagnets encompass a wide range of coordination complexes possessing
several potential applications. A formidable challenge in realizing these potential …

3d–4f heterometallic trinuclear complexes derived from amine-phenol tripodal ligands exhibiting magnetic and luminescent properties

HR Wen, PP Dong, SJ Liu, JS Liao, FY Liang… - Dalton …, 2017 - pubs.rsc.org
A new family of 3d–4f heterometallic trinuclear complexes, namely [M2LnL2]· 2ClO4· H2O
(H3L= tris (((2-hydroxy-3-methoxybenzy1) amino) ethyl) amine, where M= Ni, Ln= Gd (1), Dy …

The effect of co-ligands on the performance of single-molecule magnet behaviours in a family of linear trinuclear Zn–Dy–Zn complexes with a compartmental Schiff …

R Nandy, Z Jagličić, NC Jana, P Brandão… - Dalton …, 2024 - pubs.rsc.org
We present herein magneto-structural studies of three heterometallic Zn2Dy
complexes:[Zn2Dy (L) 2Cl2 (H2O)](ClO4)· 4H2O (1),[Zn2Dy (L) 2Br2 (H2O)](ClO4)· 4H2O (2) …

Decanuclear Ln10 Wheels and Vertex‐Shared Spirocyclic Ln5 Cores: Synthesis, Structure, SMM Behavior, and MCE Properties

S Das, A Dey, S Kundu, S Biswas… - … A European Journal, 2015 - Wiley Online Library
The reaction of a Schiff base ligand (LH3) with lanthanide salts, pivalic acid and
triethylamine in 1: 1: 1: 3 and 4: 5: 8: 20 stoichiometric ratios results in the formation of …

Dinuclear lanthanide–lithium complexes based on fluorinated β-diketonate with acetal group: Magnetism and effect of crystal packing on mechanoluminescence

DN Bazhin, YS Kudyakova, AS Bogomyakov… - Inorganic Chemistry …, 2019 - pubs.rsc.org
The synthesis of novel dinuclear lanthanide complexes with formulas [(LnL3)(LiL)(MeOH)](1–
3) and [(LnL3)(LiL)(H2O)](4–6)(Ln= Eu (III), Tb (III), Dy (III)) based on functionalized lithium β …