Phase-Pure Zirconium Metal–Organic Polyhedra Enabled by a Ligand Substitution Strategy

MG Sullivan, HK Welgama, MR Crawley… - Chemistry of …, 2023 - ACS Publications
Zirconium-based metal–organic polyhedra (ZrMOPs) are attractive due to their high
stabilities, low-cost building blocks, and solubilities relative to their metal–organic framework …

(Bio) Functionalisation of Metal–Organic Polyhedra by Using Click Chemistry

L Hernández‐López, C von Baeckmann… - … A European Journal, 2023 - Wiley Online Library
The surface chemistry of Metal–Organic Polyhedra (MOPs) is crucial to their
physicochemical properties because it governs how they interact with external substances …

Humidity‐Induced Self‐Oscillating and Self‐Healing Hypercrosslinked Metal–Organic Polyhedra Membranes

J Li, Z Liu, J Liu, X Liu, Y Luo, J Liang… - Advanced …, 2024 - Wiley Online Library
Designing autonomously oscillating materials is highly desirable for emerging smart
material fields but challenging. Herein, a type of hypercrosslinked metal–organic polyhedra …

Charge-transfer complexation of coordination cages for enhanced photochromism and photocatalysis

G Li, Z Du, C Wu, Y Liu, Y Xu, R Lavendomme… - Nature …, 2025 - nature.com
Intensified host-guest electronic interplay within stable metal-organic cages (MOCs)
presents great opportunities for applications in stimuli response and photocatalysis. Zr …

Metal–Organic Polyhedra and Metal–Organic Frameworks: Understanding How Discrete Versus Extended Structure Impacts Surface Areas and Pore Size …

HK Welgama, A Avasthi, TR Cook - Chemistry of Materials, 2024 - ACS Publications
Certain discrete metal–organic polyhedra (MOPs) contain pores that also appear in
extended metal–organic frameworks (MOFs) and MOP-based supramolecular frameworks …

Tunable synthesis of heteroleptic zirconium-based porous coordination cages

MN Morey, CM Montone, MR Dworzak, GPA Yap… - Chemical …, 2025 - pubs.rsc.org
Zirconium-based porous coordination cages have been widely studied and have shown to
be potentially useful for many applications as a result of their tunability and stability, likely as …

Construction of 2D layered metal‐organic frameworks based on the norbornene‐derived ligand with fascinating magnetic and luminescent properties

S Ding, C Zhang, J Yin, T Zhao, P Zhu, R Sun… - …, 2023 - Wiley Online Library
Three new two‐dimensional metal‐organic frameworks (MOFs), namely [Cu3 (NDIC) 3⋅
C2H5OH⋅ 2H2O] n (1),[Co2 (NDIC) 2⋅ 2 C3H7NO⋅ H2O] n⋅ nC2H5OH (2) and [(Zn3O) 2 …

[PDF][PDF] Click Chemistry

L Hernández-López, C von Baeckmann… - Chem. Eur. J, 2023 - core.ac.uk
Rh (II)-based MOP with 24 available surface alkyne groups was synthesised. Each of the 24
alkyne groups on the surface of the “clickable” Rh-MOP can react with azide-containing …

Improving the Cellular Internalization of Zr (IV) Nanocages by Tuning Hydrophilicity and Lipophilicity

S Du, J Lyu, Z Yu, K Su, W Wang, X Zhang… - Angewandte Chemie … - Wiley Online Library
Nanoscale molecular materials have emerged as a new class of compounds at the
nanometer scale with well‐defined chemical structures, remarkable uniformity and high …