Applications of halogen-atom transfer (XAT) for the generation of carbon radicals in synthetic photochemistry and photocatalysis

F Juliá, T Constantin, D Leonori - Chemical Reviews, 2021 - ACS Publications
The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Seeing the light: advancing materials chemistry through photopolymerization

N Corrigan, J Yeow, P Judzewitsch… - Angewandte Chemie …, 2019 - Wiley Online Library
The application of photochemistry to polymer and material science has led to the
development of complex yet efficient systems for polymerization, polymer post …

Photoinduced controlled/living polymerizations

C Aydogan, G Yilmaz, A Shegiwal… - Angewandte …, 2022 - Wiley Online Library
The application of photochemistry in polymer synthesis is of interest due to the unique
possibilities offered compared to thermochemistry, including topological and temporal …

Red-light-driven atom transfer radical polymerization for high-throughput polymer synthesis in open air

X Hu, G Szczepaniak… - Journal of the …, 2023 - ACS Publications
Photoinduced reversible-deactivation radical polymerization (photo-RDRP) techniques offer
exceptional control over polymerization, providing access to well-defined polymers and …

Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis

G Szczepaniak, J Jeong, K Kapil, S Dadashi-Silab… - Chemical …, 2022 - pubs.rsc.org
Photoinduced atom transfer radical polymerization (photo-ATRP) has risen to the forefront of
modern polymer chemistry as a powerful tool giving access to well-defined materials with …

Porphyrinic Zirconium Metal–Organic Frameworks (MOFs) as Heterogeneous Photocatalysts for PET‐RAFT Polymerization and Stereolithography

L Zhang, X Shi, Z Zhang, RP Kuchel… - Angewandte Chemie …, 2021 - Wiley Online Library
In this study, porphyrinic zirconium (Zr) MOFs were investigated as heterogeneous
photocatalysts for photoinduced electron transfer‐reversible addition‐fragmentation chain …

Role of external field in polymerization: mechanism and kinetics

YN Zhou, JJ Li, YY Wu, ZH Luo - Chemical reviews, 2020 - ACS Publications
The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …

Conjugated cross-linked phenothiazines as green or red light heterogeneous photocatalysts for copper-catalyzed atom transfer radical polymerization

S Dadashi-Silab, F Lorandi, MJ DiTucci… - Journal of the …, 2021 - ACS Publications
Using the power of light to drive controlled radical polymerizations has provided significant
advances in synthesis of well-defined polymers. Photoinduced atom transfer radical …

Evolution and future directions of metal-free atom transfer radical polymerization

EH Discekici, A Anastasaki, J Read de Alaniz… - …, 2018 - ACS Publications
The increasing impact of atom transfer radical polymerization (ATRP) in fields beyond
traditional polymer science has necessitated the development of alternative strategies for …