Topology Matters: Conformation and Microscopic Dynamics of Ring Polymers

M Kruteva, J Allgaier, D Richter - Macromolecules, 2023 - ACS Publications
Ring polymers have fascinated theorists, simulators, and experimentalists as they are the
simplest polymer without ends, giving rise to important topology related properties. We …

Kinetoplast DNA: a polymer physicist's topological Olympic dream

D Michieletto - Nucleic Acids Research, 2024 - academic.oup.com
All life forms are miraculous, but some are more inexplicable than others. Trypanosomes are
by far one of the most puzzling organisms on Earth: their mitochondrial genome, also called …

Unified understanding of the impact of semiflexibility, concentration, and molecular weight on macromolecular-scale ring diffusion

B Mei, GS Grest, S Liu, TC O'Connor… - Proceedings of the …, 2024 - pnas.org
Conformationally fluctuating, globally compact macromolecules such as polymeric rings,
single-chain nanoparticles, microgels, and many-arm stars display complex dynamic …

Cluster Formation in Solutions of Polyelectrolyte Rings

R Staňo, J Smrek, CN Likos - ACS nano, 2023 - ACS Publications
We use molecular dynamics simulations to explore concentrated solutions of semiflexible
polyelectrolyte ring polymers, akin to the DNA mini-circles, with counterions of different …

Mixing linear polymers with rings and catenanes: Bulk and interfacial behavior

R Staňo, CN Likos, SA Egorov - Macromolecules, 2023 - ACS Publications
We derive and parameterize effective interaction potentials between a multitude of different
types of ring polymers and linear chains, varying the bending rigidity and solvent quality for …

Measuring topological constraint relaxation in ring-linear polymer blends

DL Vigil, T Ge, M Rubinstein, TC O'Connor, GS Grest - Physical Review Letters, 2024 - APS
Polymers are an effective test bed for studying topological constraints in condensed matter
due to a wide array of synthetically available chain topologies. When linear and ring …

Influence of Nanoparticles on the Structure, Dynamics, and Mechanical Behavior of Nonconcatenated Ring Polymers

T Yue, H Zhao, Y Wei, P Duan, L Zhang, J Wang… - …, 2024 - ACS Publications
The structure and dynamics of polymers in the presence of nanoparticles (NPs) determine
the macroscopic properties of polymer–nanoparticle composites (PNCs). Through molecular …

Geometric learning of knot topology

JL Sleiman, F Conforto, YAG Fosado, D Michieletto - Soft Matter, 2024 - pubs.rsc.org
Knots are deeply entangled with every branch of science. One of the biggest open
challenges in knot theory is to formalise a knot invariant that can unambiguously and …

Supercoiled ring polymers under shear flow

C Schneck, J Smrek, CN Likos, A Zöttl - Nanoscale, 2024 - pubs.rsc.org
We apply monomer-resolved computer simulations of supercoiled ring polymers under
shear, taking full account of the hydrodynamic interactions, accompanied, in parallel, by …

Unraveling the Glass-like Dynamic Heterogeneity in Ring Polymer Melts: From Semiflexible to Stiff Chain

S Goto, K Kim, N Matubayasi - ACS Polymers Au, 2023 - ACS Publications
Ring polymers are an intriguing class of polymers with unique physical properties, and
understanding their behavior is important for developing accurate theoretical models. In this …