Pyrolysis study of dimethyl carbonate, diethyl carbonate, and ethyl methyl carbonate using shock-tube spectroscopic CO measurements and chemical kinetics …

CM Grégoire, SP Cooper, M Khan-Ghauri… - Combustion and …, 2023 - Elsevier
The pyrolysis of three linear carbonates-dimethyl carbonate (DMC), diethyl carbonate
(DEC), and ethyl methyl carbonate (EMC)-was investigated behind reflected shock waves …

Experimental study of ethanol oxidation behind reflected shock waves: Ignition delay time and H2O laser-absorption measurements

O Mathieu, LT Pinzón, TM Atherley, CR Mulvihill… - Combustion and …, 2019 - Elsevier
The oxidation of ethanol was investigated in shock tubes by measuring ignition delay times
and water time history profiles. A laser absorption technique was used in the latter case …

Shock tube study of ethanol pyrolysis I: Multi-species time-history measurements

R Choudhary, V Boddapati, S Clees, JJ Girard… - Combustion and …, 2021 - Elsevier
Time-histories of the concentration of major products of ethanol pyrolysis at 1 atm and 10
atm in the temperature range of 1200–1600 K were measured behind reflected shock waves …

Speciation measurements in shock tubes for validation of complex chemical kinetics mechanisms: Application to 2-Methyl-2-Butene oxidation

SA Alturaifi, CR Mulvihill, O Mathieu, EL Petersen - Combustion and Flame, 2021 - Elsevier
Shock-tube species time histories can be used to generate multiple validation targets to
develop and validate detailed chemical kinetics mechanisms. In this study, new shock-tube …

High-pressure shock tube study of ethanol oxidation: Ignition delay time and CO time-history measurements

AR Laich, E Ninnemann, S Neupane, R Rahman… - Combustion and …, 2020 - Elsevier
Ethanol oxidation was studied by measuring CO time-histories and ignition delay times
behind reflected shockwaves at elevated pressures. In this study, experimental conditions …

Interference-free laser-based temperature and CO-concentration measurements for shock-heated isooctane and isooctane/ethanol blends

D He, T Si, M Fikri, X Luo - Measurement Science and …, 2023 - iopscience.iop.org
Species concentration (eg CO) and temperature measurements in the combustion field
require fast-response technique without interfering species. In the last decade, tunable …

Shock tube investigation of high-temperature, extremely-rich oxidation of several co-optima biofuels for spark-ignition engines

RK Rahman, S Barak, SW Wagnon, G Kukkadapu… - Combustion and …, 2022 - Elsevier
To reduce the reliance on fossil fuels in the transportation sector and increase combustion
efficiency, the Co-Optima initiative from US Department of Energy identified the top 10 …

Ignition delay time and H2O measurements during methanol oxidation behind reflected shock waves

LT Pinzón, O Mathieu, CR Mulvihill, I Schoegl… - Combustion and …, 2019 - Elsevier
To improve detailed chemical kinetics models, the oxidation of methanol was investigated
behind reflected shock waves in shock tubes. Ignition delay times of methanol–air mixtures …

Simultaneous temperature and CO-concentration time-history measurements during the pyrolysis and ultra-fuel-rich oxidation of ethanol, diethyl ether, n-heptane, and …

D He, Y Ding, L Shi, D Zheng, Z Peng - Combustion and Flame, 2021 - Elsevier
This study used shock tube and laser absorption spectroscopy to simultaneously measure
temperature and CO-concentration time-histories behind reflected shock waves during the …

Experimental study of the formation of CO during ethanol pyrolysis and dry reforming with CO2

O Mathieu, CM Grégoire, M Khan-Ghauri… - Applications in Energy …, 2022 - Elsevier
To use piston engines and their pressure and temperature histories as a chemical rector to
produce valuable chemicals, accurate chemical kinetics models are necessary so the …