Recent advances in borenium catalysis

X Tan, H Wang - Chemical Society Reviews, 2022 - pubs.rsc.org
Borenium ions are strong Lewis acids because of the positive charge on boron. While their
high reactivity had long restricted their role in organic synthesis to stoichiometric reagents, in …

Electron-deficient cyclopropenium cations as Lewis acids in FLP chemistry

D Mandal, ZW Qu, S Grimme… - Chemical …, 2023 - pubs.rsc.org
Cyclopropenium cations incorporating electron deficient substituents are Lewis acidic
despite the presence of π-electrons. The chloride and electron affinities are examined …

Preparation of arylboronic and diarylborinic acids from potassium aryl (fluoro) borates

VV Bardin, NY Adonin - Monatshefte für Chemie-Chemical Monthly, 2024 - Springer
Preparation of arylboronic and diarylborinic acids from potassium aryl(fluoro)borates |
Monatshefte für Chemie - Chemical Monthly Skip to main content SpringerLink Account Menu …

Cationic Compounds of Group 13 Elements: Entry Point to the p‐block for Modern Lewis Acid Reagents

S Singh, M Bhandari, S Rawat… - Polar Organometallic …, 2022 - Wiley Online Library
This chapter provides an overview of the recent developments in the synthetic,
characterization, reactivity studies, and applications of group 13 metal cationic complexes …

5.4 Recent Advancements in Catalytic Applications of Cationic Group 13 Complexes

H Borane - Polar Organometallic Reagents, 2022 - Wiley Online Library
Hydroboration is one of the most prominent and fundamental reactions and has been widely
explored with a range of catalysts. The prominent reports on hydroboration using …

Borocations in catalysis

K Stefkova, L Gierlichs, D Willcox… - … of Inorganic and …, 2011 - Wiley Online Library
Even in its infancy, the catalytic application of cationic boron species has proven itself a
powerful tool for main group catalyzed element bond activation. Though these highly Lewis …

[PDF][PDF] Chiral'Frustrated Lewis Pair'Systems for Practical Enantioselective Hydrogenation and Hydrosilylation

DM Mercea - 2019 - core.ac.uk
Abstract The chemistry of 'Frustrated Lewis Pairs'(FLPs) has been the subject of intense
investigation for over a decade now, this activity following the seminal report of Stephan et …

Carbenes and Nitrenes

E Gras, S Chassaing - … 2019: An annual survey covering the …, 2023 - Wiley Online Library
A general review has appeared on catalyst design assisted by computations featuring some
examples of carbenes acting either as organocatalysts or in situ generated reagents in metal …

[引用][C] Don't overthink things too much and trust yourself more often

B Huchenski - 2021 - Dalhousie University Halifax