Methyltrioxorhenium and its applications in olefin oxidation, metathesis and aldehyde olefination

FE Kühn, A Scherbaum, WA Herrmann - Journal of organometallic …, 2004 - Elsevier
Organorhenium (VII) oxides, most notably methyltrioxorhenium (MTO) and several of its
derivatives gained significant importance as extremely versatile catalysts for olefin oxidation …

Organorhenium (VII) and organomolybdenum (VI) oxides: syntheses and application in olefin epoxidation

FE Kühn, AM Santos, WA Herrmann - Dalton Transactions, 2005 - pubs.rsc.org
The first members of the classes of the organorhenium (VII) oxides and organomolybdenum
(VI) oxides were described during the 1960s and 1970s. However, despite the fact that …

An effective procedure for the synthesis of acid-sensitive epoxides: Use of 1-methylimidazole as the additive on methyltrioxorhenium-catalyzed epoxidation of alkenes …

S Yamazaki - Organic & biomolecular chemistry, 2010 - pubs.rsc.org
An effective method for suppression of ring opening and rearrangement of acid-sensitive
epoxides during methyltrioxorhenium (MTO)-catalyzed epoxidation of alkenes with H2O2 by …

Highly efficient C–H insertion reactions of hydrogen peroxide catalyzed by homogeneous and heterogeneous methyltrioxorhenium systems in ionic liquids

G Bianchini, M Crucianelli, F De Angelis, V Neri… - Tetrahedron letters, 2005 - Elsevier
A convenient and efficient C–H insertion reaction of environment friendly H2O2 into
representative hydrocarbon derivatives by homogeneous methyltrioxorhenium (MTO) …

Methyltrioxorhenium Interactions with Lewis Acid Sites of an Amorphous Silica− Alumina

AW Moses, NA Ramsahye, C Raab, HD Leifeste… - …, 2006 - ACS Publications
Deposition of CH3ReO3 onto the dehydrated surface of an amorphous silica− alumina
(Si/Al= 4.8) generates a catalyst for olefin metathesis, although CH3ReO3 itself is not active …

Dendrimer crown-ether tethered multi-wall carbon nanotubes support methyltrioxorhenium in the selective oxidation of olefins to epoxides

BM Bizzarri, A Fanelli, L Botta, C Sadun, L Gontrani… - RSC Advances, 2020 - pubs.rsc.org
Benzo-15-crown-5 ether supported on multi-wall carbon nanotubes (MWCNTs) by tethered
poly (amidoamine)(PAMAM) dendrimers efficiently coordinated methyltrioxorhenium in the …

On the way to chiral epoxidations with methyltrioxorhenium (VII) derived catalysts

JJ Haider, RM Kratzer, WA Herrmann, J Zhao… - Journal of …, 2004 - Elsevier
Methyltrioxorhenium (VII)(MTO) is successfully applied as chiral epoxidation catalysts in the
presence of H2O2 as oxidizing agent and excess chiral Lewis base ligands derived from …

Lewis acidity of methyltrioxorhenium (VII)(MTO) based on the relative binding strengths of N-donors

SM Nabavizadeh, M Rashidi - Journal of the American Chemical …, 2006 - ACS Publications
This article presents a σ acceptor strength scale for methyltrioxorhenium (VII)(MTO), one of
the most versatile and useful high oxidation state organometallics ever described. The …

Correlation between equilibrium constant and stabilization energy: A combined approach based on chemical thermodynamics, statistical thermodynamics, and density …

A Hamid, RK Roy - The Journal of Physical Chemistry A, 2020 - ACS Publications
In the present work, an attempt is made to establish the correlation between equilibrium
constant and stabilization energy [Δ E SE (AB)] generated from density functional reactivity …

Mono-and bis-methyltrioxorhenium (VII) complexes with salen ligands: Synthesis, properties, applications

Z Xu, MD Zhou, M Drees, H Chaffey-Millar… - Inorganic …, 2009 - ACS Publications
Methyltrioxorhenium (VII)(MTO) forms 1: 1 (mono-) or/and 2: 1 (bis-) complexes with salen
ligands, undergoing a hydrogen transfer from a ligand-bound OH-group to a ligand nitrogen …