Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

The comparison between single atom catalysis and surface organometallic catalysis

MK Samantaray, V D'Elia, E Pump, L Falivene… - Chemical …, 2019 - ACS Publications
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …

Surface organometallic chemistry in heterogeneous catalysis

MK Samantaray, E Pump… - Chemical Society …, 2018 - pubs.rsc.org
The broad challenges of energy and environment have become a main focus of research
efforts to develop more active and selective catalytic systems for key chemical …

Small molecule activation with bimetallic systems: a landscape of cooperative reactivity

M Navarro, JJ Moreno, M Pérez-Jiménez… - Chemical …, 2022 - pubs.rsc.org
There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …

[HTML][HTML] Surface science approach to the heterogeneous cycloaddition of CO2 to epoxides catalyzed by site-isolated metal complexes and single atoms: a review

V D'Elia, AW Kleij - Green Chemical Engineering, 2022 - Elsevier
The cycloaddition of CO 2 to epoxides to afford cyclic organic carbonates is an increasingly
relevant non-reductive strategy to convert CO 2 to useful products able to serve as high …

Isolated metal atoms and clusters for alkane activation: Translating knowledge from enzymatic and homogeneous to heterogeneous systems

L Liu, A Corma - Chem, 2021 - cell.com
Activation of alkanes can be achieved with different types of catalysts, spanning over
enzymes, homogeneous and heterogeneous metal catalysts. Though a tremendous amount …

Solid catalysts for the dehydrogenation of long-chain alkanes: lessons from the dehydrogenation of light alkanes and homogeneous molecular catalysis

H Wan, N Gong, L Liu - Science China Chemistry, 2022 - Springer
Long-chain alkanes are abundant feedstocks supplied by natural resources and chemical
industry. Specially, normal long-chain alkanes are primary products from Fischer—Tropsch …

Metal–Metal Synergy in Well-Defined Surface Tantalum–Iridium Heterobimetallic Catalysts for H/D Exchange Reactions

S Lassalle, R Jabbour, P Schiltz… - Journal of the …, 2019 - ACS Publications
A novel heterobimetallic tantalum/iridium hydrido complex,[{Ta (CH2 t Bu) 3}{IrH2 (Cp*)}] 1,
featuring a very short metal–metal bond, has been isolated through an original alkane …

Propane metathesis and hydrogenolysis over titanium hydride catalysts

M Huang, Y Tomimuro, S Miyazaki, S Mine… - Catalysis Science & …, 2023 - pubs.rsc.org
Propane metathesis reactions over group 2–5 metal hydrides were investigated. Among the
tested metal hydrides, TiH2 exhibited the highest butane yield as a metathesis reaction …

Surface organometallic chemistry: A sustainable approach in modern catalysis

MK Samantaray, SK Mishra, A Saidi… - Journal of Organometallic …, 2021 - Elsevier
Surface organometallic chemistry (SOMC) is an established concept, associated with
specific tools for the characterization of a well-defined single-site catalysts. Primarily …