1. History 3422. Activation barriers 3432.1 Redox potentials 3442.2 Reorganization energy
3443. Electronic coupling 3454. Ru-modified proteins 3484.1 Reorganization energy …

Electron transfers in photosynthesis and respiration commonly occur between metal-
containing cofactors that are separated by large molecular distances. Understanding the …

Recent investigations have shed much light on the nuclear and electronic factors that control
the rates of long-range electron tunneling through molecules in aqueous and organic …

Computer simulations of biological electron transfer reactions are reviewed with a focus on
the calculation of reaction free energy (driving force) and reorganization free energy. Then a …

Long-range electron transfer reactions have been actively discussed in the past decade in
the context of electron transport in biological membranes. 1, 2 Recent experimental work …

The acceleration of electron transfer (ET) rates in redox proteins relative to aqueous solutes
can be attributed to the protein's ability to reduce the nuclear response or reorganization …

We have calculated the reorganization energy for the intramolecular electron transfer
between the reduced type 1 copper site and the peroxy intermediate of the trinuclear cluster …

To explore the possibility of electron transport in a recently designed four-helix bundle
protein (Cochran, FV; et al. J. Am. Chem. Soc. 2005, 127, 1346), we have computed the …

Abstract Analysis of electron-transfer (ET) kinetics data obtained from experiments on Ru-
modified proteins (azurin, cytochrome c, myoglobin) and the bacterial photosynthetic …

The rates of electron-transfer reactions can be systematically varied by application of
external electric fields. The electric field effect on the charge recombination rate constant of …