Catalyst engineering empowers the creation of biomass-derived polyesters and polycarbonates

A Brandolese, AW Kleij - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus The introduction of circular principles in chemical manufacturing will drastically
change the way everyday plastics are produced, thereby affecting several aspects of the …

Anionic polymerization of terpene monomers: New options for bio-based thermoplastic elastomers

C Wahlen, H Frey - Macromolecules, 2021 - ACS Publications
Biomass-derived materials possess vast potential for material science and industry in the
next decades. Dwindling fossil resources and an increasing environmental awareness …

Nitrogen‐containing polymers derived from terpenes: possibilities and limitations

FCM Scheelje, FC Destaso, H Cramail… - Macromolecular …, 2023 - Wiley Online Library
Nitrogen‐containing polymers are widely applied materials, including polyamides,
polyurethanes, and polyureas as well as epoxy thermosets. Their indispensability and the …

4D Photopolymers Derived From Ring-Opening Copolymerization of Cyclic Anhydrides and Limonene Oxide

S Brooks, D Merckle, AC Weems - ACS Sustainable Chemistry & …, 2023 - ACS Publications
Natural product-derived materials are a growing source of interest for bioderived polymers
or materials with improved sustainability profiles, but only recently have such materials truly …

A highly active, thermally robust iron (iii)/potassium (i) heterodinuclear catalyst for bio-derived epoxide/anhydride ring-opening copolymerizations

WT Diment, G Rosetto, N Ezaz-Nikpay, RWF Kerr… - Green …, 2023 - pubs.rsc.org
The ring-opening copolymerization (ROCOP) of epoxides and anhydrides is a useful route
to polyesters but requires more active catalysts. An iron (III)/potassium (I) catalyst, applied …

Renewable Beta‐Elemene Based Cyclic Carbonates for the Preparation of Oligo (hydroxyurethane) s

C Maquilón, A Brandolese, C Alter… - …, 2022 - Wiley Online Library
Conversion of β‐elemene into new β‐elemene dicarbonates through epoxidation and halide
salt‐catalyzed CO2 cycloaddition reactions is reported. Step‐growth polyaddition of this …

Catalytic Ring-Opening Copolymerization of Fatty Acid Epoxides: Access to Functional Biopolyesters

A Brandolese, F Della Monica, MA Pericàs… - …, 2022 - ACS Publications
Fatty acid epoxies serve as valuable starting materials for the development of bio-based
polyesters. Here we present a new and efficient catalytic process that allows for the …

Supercritical CO2 as an Efficient Medium for Macromolecular Carbonate Synthesis through Ring-Opening Co- and Teroligomerization

DH Lamparelli, I Grimaldi… - ACS Sustainable …, 2023 - ACS Publications
Ring-opening polymerization and teroligomerization processes that involve two different
epoxides and carbon dioxide are significantly more efficiently executed in a supercritical …

Linalool derivatives for natural product-based 4D printing resins

D Merckle, E Constant, AC Weems - ACS Sustainable Chemistry …, 2021 - ACS Publications
The use of green alternatives to petrochemicals from renewable feedstocks is of great
interest globally, especially within additive manufacturing efforts. To this end, the utilization …

Synthesis of Biorenewable Terpene Monomers Using Enzymatic Epoxidation under Heterogeneous Batch and Continuous Flow Conditions

A Brandolese, DH Lamparelli… - ACS Sustainable …, 2023 - ACS Publications
A commercially available Lipase B from Candida antarctica immobilized onto a
macroporous support (Novozym 435) has been employed in the presence of H2O2 as a …