Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory

AA Fokin, PR Schreiner - Chemical reviews, 2002 - ACS Publications
As the main constituent of natural gas, alkanes are arguably Nature's most plentiful organic
base chemicals that are easily accessible. Chemists have long coveted the use of alkanes …

Electron transfer initiated reactions: Bond formation and bond dissociation

A Houmam - Chemical reviews, 2008 - ACS Publications
Electron transfer reactions are among the most elementary of all chemical reactions and
play a fundamental role in many areas including organic synthesis, biological processes …

Photocatalytic generation of aminium radical cations for C–N bond formation

JM Ganley, PRD Murray, RR Knowles - ACS catalysis, 2020 - ACS Publications
Aminium radical cations have been extensively studied as electrophilic aminating species
that readily participate in C–N bond forming processes with alkenes and arenes. However …

[图书][B] Organic electrochemistry

O Hammerich, B Speiser - 2016 - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

[图书][B] CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2

WM Horspool, F Lenci - 2003 - taylorfrancis.com
The second edition of this best-selling handbook is bigger, more comprehensive, and now
completely current. In addition to thorough updates to the discussions featured in the first …

The Photocatalyzed Aza-Henry Reaction of N-Aryltetrahydroisoquinolines: Comprehensive Mechanism, H- versus H+-Abstraction, and Background Reactions

H Bartling, A Eisenhofer, B König… - Journal of the …, 2016 - ACS Publications
The cross-dehydrogenative coupling (CDC) reaction of N-aryltetrahydroisoquinolines (THIQ)
is one of the most exploited photocatalytic transformation and a test reaction for an …

Photocatalytic oxygenation of anthracenes and olefins with dioxygen via selective radical coupling using 9-mesityl-10-methylacridinium ion as an effective electron …

H Kotani, K Ohkubo, S Fukuzumi - Journal of the American …, 2004 - ACS Publications
Visible light irradiation of the absorption band of 9-mesityl-10-methylacridinium ion (Acr+−
Mes) in an O2-saturated acetonitrile (MeCN) solution containing 9, 10-dimethylanthracene …

Minimization of Back‐Electron Transfer Enables the Elusive sp3 C−H Functionalization of Secondary Anilines

H Zhao, D Leonori - Angewandte Chemie International Edition, 2021 - Wiley Online Library
Anilines are some of the most used class of substrates for application in photoinduced
electron transfer. N, N‐Dialkyl‐derivatives enable radical generation α to the N‐atom by …

Photoalkylation of 10-alkylacridinium ion via a charge-shift type of photoinduced electron transfer controlled by solvent polarity

S Fukuzumi, K Ohkubo, T Suenobu… - Journal of the …, 2001 - ACS Publications
A charge-shift type of photoinduced electron-transfer reactions from various electron donors
to the singlet excited state of 10-decylacridinium cation (DeAcrH+) in a nonpolar solvent …

Visible‐light‐mediated aromatic substitution reactions of cyanoarenes with 4‐Alkyl‐1, 4‐dihydropyridines through double carbon–carbon bond cleavage

K Nakajima, S Nojima, K Sakata… - ChemCatChem, 2016 - Wiley Online Library
Novel aromatic substitution reactions of cyanoarenes with 4‐alkyl‐1, 4‐dihydropyridines as
alkylating reagents in the presence of a catalytic amount of a photoredox catalyst proceed …