Over the past few decades, there has been tremendous interest in the chemistry of arenes
coordinated to transition metal moieties due to their applications in the fields of organic and …

Photolysis of RuCp (benzene)+ in CH3CN at 313 nm gives a quantitative yield of [RuCp
(CH3CN) 3]+ which is isolated as the PF6" salt. The quantum yield for this reaction is …

Although the first report on [2, 2] paraeyclophane (4) was its isolation from a polymer and its
identity was established by an x-ray analysis i-3), the development of eyclophane chemistry …

The discovery of the transition metal sandwich structure'-'in compounds such as
ferrocene'and bis benzene chromium'thirty years ago was a major advance in organic and …

Gas-phase pyrolysis of benzo [l, 2; 4, 5] dicyclobutene (4) in a nitrogen stream at 425 C
gives [24](l, 2, 4, 5) cyclophane (7),[26](l, 2, 4, 5) cyclophane (10, deltaphane), and 14, 20 …

The first 30-electron triple-decker complexes of the iron group metals [(η-C 5 R 5) M (μ, η-C
5 Me 5) M′(η-C 5 Me 5)] PF 6 were synthesized by reaction of [Fe (η-C 5 H 5)(η-C 6 H 6)] …

In this survey, the current status of knowledge with regards to the structures and reactivities
of photoinitiators for epoxies is presented. Especially aryldiazonium, diphenyliodonium …

A sixfold alkyl chain extension, the reaction of 1 with tBuOK and H 2 C CH CH 2 Br in
THF to give 2, was achieved in one step in quantitative yield. The Fe II center of 2 can be …

Easy accessibility of Cb∗ Co (CO) 2I (1, Cb∗= C 4Me 4), which can be prepared in one-pot
from Co2 (CO) 8 and 2-butyne, facilitates the development of chemistry of the Cb∗ Co …

The temporary complexation of aromatics by the FeCp n+ or FeC 6 R 6 m+ units (R= H or
CH 3; n= 0 or 1; m= 0–2) activates the formation of many CC and C-element bonds. This …