The activation and utilization of substrates mediated by Frustrated Lewis Pairs (FLPs) was
initially believed to occur solely via a two-electron, cooperative mechanism. More recently …

The utilization of aryl radicals as open‐shelled intermediates has become an essential tool
for both conventional and state‐of‐the‐art synthetic chemistry. However, the current …

We report a photoredox system comprising sodium iodide, triphenyl phosphine, and N, N,
N′, N′-tetramethylethylenediamine (TMEDA) that can form a self-assembled tetrameric …

An unprecedented geminal olefinic dichalcogenation of alkenyl sulfonium salts with
dichalcogenides ArYYAr (Y= S, Se, Te) is reported, providing various trisubstituted 1, 1 …

The evaluation of the pentafluorocyclopropyl group as a chemotype in crop protection and
medicinal chemistry has been hampered in the past by the lack of suitable methodologies …

The introduction of the copper-catalyzed azide–alkyne coupling (CuAAC) to 1, 3-dipolar
cycloadditions was pivotal to their popularization in synthetic chemistry and to their …

Carboxylic functionalities are among the pivotal groups in bioactive molecules and in the
synthesis of new lead compounds because of their unique character in the formation of …

Aryl phosphonates are prevalent moieties in medicinal chemistry and agrochemicals. Their
chemical synthesis normally relies on the use of precious metals, harsh conditions or aryl …

Oxidative alkene functionalization reactions are a fundamental class of complexity‐building
organic transformations. However, the majority of established approaches rely on …

A visible-light-induced metal-free trifluoromethylselenolation of aryl iodides and bromides
with [Me4N][SeCF3] is described. The reaction was conducted at ambient temperature by …