Recent advances in polyoxometalate-based heterogeneous catalytic materials for liquid-phase organic transformations

Y Zhou, G Chen, Z Long, J Wang - RSC advances, 2014 - pubs.rsc.org
Polyoxometalates (POMs) are a unique class of molecular metal oxides with a tunable
structure at the atomic level. They have demonstrated various potential applications in …

Highly efficient catalytic production of oximes from ketones using in situ–generated H2O2

RJ Lewis, K Ueura, X Liu, Y Fukuta, TE Davies… - Science, 2022 - science.org
The ammoximation of cyclohexanone using preformed hydrogen peroxide (H2O2) is
currently applied commercially to produce cyclohexanone oxime, an important feedstock in …

Recent advances in applications of POMs and their hybrids in catalysis

S Sadjadi, M M. Heravi - Current Organic Chemistry, 2016 - benthamdirect.com
Polyoxometalates (POMs) and their hybrid systems are green and efficient catalysts which
have found a wide range of application, due to their outstanding properties such as high …

Heterogeneous catalysis by tungsten-based heteropoly compounds

A Enferadi-Kerenkan, TO Do… - Catalysis Science & …, 2018 - pubs.rsc.org
Tungsten, a fascinating metal, has found a variety of catalytic applications in the form of
tungsten sulfides, simple tungsten oxides (eg tungsten trioxide, tungstate, tungstic acid …

Thermal hazards of benzaldehyde oxime: Based on decomposition products and kinetics analysis by adiabatic calorimeter

XQ Zhao, WQ Wu, H Li, ZC Guo, WH Chen… - Process Safety and …, 2021 - Elsevier
As a self-reactive substance, benzaldehyde oxime (BO) is prone to a highly exothermic
runaway reaction and thermal hazard analysis and the reaction kinetics calculation of BO …

A Synergic Activity of Urea/Butyl Imidazolium Ionic Liquid Supported on UiO-66-NH2 Metal–Organic Framework for Synthesis of Oximes

S Askari, M Jafarzadeh, DB Christensen, S Kegnæs - Catalysis Letters, 2020 - Springer
An efficient supported ionic liquid catalyst is designed for condensation reaction of
aldehydes and ketones. The Zr-based metal–organic framework (MOF), UiO-66-NH 2, was …

Continuous three-phase 2-butanone ammoximation process via spray forming TS-1 microspheres in a highly efficient jet loop reactor

Q Chu, P Wang, G He, M Li, H Zhu, R Liu… - Chemical Engineering …, 2017 - Elsevier
A highly efficient jet loop reactor with ceramic membrane as a separator for a continuous
three-phase system was developed to enhance the mass and heat transfer of ammoximation …

Nickel-modified TS-1 catalyzed the ammoximation of methyl ethyl ketone

D Yang, H Wang, W Wang, S Peng, X Yang, X Xu, S Jia - Catalysts, 2019 - mdpi.com
In this paper, five kinds of transition metal-modified titanium silicalite-1 (M-TS-1) were
prepared by an ultrasonic impregnation method. We studied their catalytic performances in …

A novel and efficient catalytic system including TEMPO/acetaldoxime/InCl3 for aerobic oxidation of primary amines to oximes

J Yu, X Cao, M Lu - Tetrahedron Letters, 2014 - Elsevier
A simple and efficient catalytic system including TEMPO/acetaldoxime/InCl 3 for aerobic
oxidation of primary amines to corresponding oximes by using toluene as the solvent is …

An integrated process for the synthesis of solid hydroxylamine salt with ammonia and hydrogen peroxide as raw materials

Y Xu, Z Li, L Gao, D Zhang, X Zhao… - Industrial & …, 2015 - ACS Publications
An integrated process was designed for the synthesis of hydroxylamine salt with ammonia
and hydrogen peroxide as raw materials; that is, hydroxylamine is produced from a …