Pnictogen bonding in coordination chemistry
The pnictogen bond (PnB) is a noncovalent attraction between electrophilic pnictogen
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
Catalytic hydrodefluorination via oxidative addition, ligand metathesis, and reductive elimination at Bi (I)/Bi (III) centers
Y Pang, M Leutzsch, N Nöthling… - Journal of the …, 2021 - ACS Publications
Herein, we report a hydrodefluorination reaction of polyfluoroarenes catalyzed by
bismuthinidenes, Phebox-Bi (I) and OMe-Phebox-Bi (I). Mechanistic studies on the …
bismuthinidenes, Phebox-Bi (I) and OMe-Phebox-Bi (I). Mechanistic studies on the …
High Lewis Acidity at Planar, Trivalent, and Neutral Bismuth Centers
KM Marczenko, S Jee, SS Chitnis - Organometallics, 2020 - ACS Publications
Geometric perturbation away from classical structures can engender unusual frontier MO
situations leading to high Lewis acidity. Recently we reported a T-shaped bismuth triamide …
situations leading to high Lewis acidity. Recently we reported a T-shaped bismuth triamide …
Organic compounds of bismuth: synthesis, structure, and applications
The present review, describing the modern achievements in the area of synthetic methods,
investigation of specific structural features, and possibilities of practical use of the organic …
investigation of specific structural features, and possibilities of practical use of the organic …
Halogen bonding between entirely negative fluorine atoms? Evidence from the crystal packing of some gold (i) and gold (iii) complexes with extensively fluorinated m …
A Sava, KT Kegyes, BT Popuş, BC Dan, C Silvestru… - …, 2020 - pubs.rsc.org
Despite lacking positive σ-holes, fluorine atoms of perfluorophenyl rings can engage in solid
state fluorine–fluorine interactions, analogous to halogen bonding, in the absence of metal …
state fluorine–fluorine interactions, analogous to halogen bonding, in the absence of metal …
Organometallic Compounds of Arsenic, Antimony and Bismuth
J Cornella, Y Pang - Comprehensive Organometallic Chemistry IV, 2022 - pure.mpg.de
要旨 As a continuation of previous editions of COMC, this chapter covers the literature of
organometallic compounds of arsenic, antimony and bismuth between 2005 and 2020. In …
organometallic compounds of arsenic, antimony and bismuth between 2005 and 2020. In …
Synthesis and characterization of diorganoantimony (III) and-bismuth (III) halides with 2-(Et2NCH2) C6H4 and 2-(i-Pr2NCH2) C6H4 substituents
I Chircă, C Silvestru, HJ Breunig, CI Raţ - Inorganica Chimica Acta, 2018 - Elsevier
Abstract Compounds [2-(Et 2 NCH 2) C 6 H 4] 2 SbX [X= Cl (1), Br (2)] and [2-(i-Pr 2 NCH 2)
C 6 H 4] 2 EBr [E= Sb (3), Bi (4)] were prepared by coupling reactions between …
C 6 H 4] 2 EBr [E= Sb (3), Bi (4)] were prepared by coupling reactions between …
Experimental evidence for hypercoordination in triorganotelluronium halides with 2-(Me 2 NCH 2) C 6 H 4 groups
A Beleagă, E Denes, C Silvestru… - New Journal of Chemistry, 2019 - pubs.rsc.org
Heteroleptic triorganotelluronium chlorides of the type [RPh2Te]+ Cl−(1) and [R2PhTe]+
Cl−(4)[R= 2-(Me2NCH2) C6H4] were obtained by reacting Ph2TeCl2 with RLi in 1: 1 and 1 …
Cl−(4)[R= 2-(Me2NCH2) C6H4] were obtained by reacting Ph2TeCl2 with RLi in 1: 1 and 1 …
One‐Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o‐Carbonyl Iodoarenes by Zincation
T Murafuji, AFM Hafizur Rahman… - Heteroatom …, 2019 - Wiley Online Library
Diaryl (iodo) bismuthanes possessing a hypervalent C= O••• Bi–I bond were conveniently
synthesized in a one‐pot reaction by using arylzinc reagents generated from o‐carbonyl …
synthesized in a one‐pot reaction by using arylzinc reagents generated from o‐carbonyl …
Chiral Ferrocenyl-Bismuthines containing N/O donor pendant arm: Syntheses and molecular structures
Some new chiral substituted ferrocenyl bismuthines CpFe (2-[Me 2 NCH (R)] C 5 H 3)
BiPhCl where R= H (1) or Me (2) and CpFe (2-[Me 2 NCH (R)] C 5 H 3) BiPh 2 where R= H …
BiPhCl where R= H (1) or Me (2) and CpFe (2-[Me 2 NCH (R)] C 5 H 3) BiPh 2 where R= H …