Three‐Component Multiblock 1D Supramolecular Copolymers of Ir (III) Complexes with Controllable Sequences

Y Chen, Q Wan, Y Shi, B Tang… - Angewandte Chemie …, 2023 - Wiley Online Library
Multicomponent supramolecular block copolymers (BCPs) have attracted much attention
due to their potential functionalities, but examples of three‐component supramolecular …

Enzymatic Reaction-Coupled, Cooperative Supramolecular Polymerization

A Das, S Ghosh, A Mishra, A Som… - Journal of the …, 2024 - ACS Publications
Nature employs sophisticated mechanisms to precisely regulate self-assembly and functions
within biological systems, exemplified by the formation of cytoskeletal filaments. Various …

[HTML][HTML] Noncovalent synthesis of homo and hetero-architectures of supramolecular polymers via secondary nucleation

S Kotha, R Sahu, AC Yadav, P Sharma… - Nature …, 2024 - nature.com
The synthesis of supramolecular polymers with controlled architecture is a grand challenge
in supramolecular chemistry. Although living supramolecular polymerization via primary …

Controlled Supramolecular Polymerization via Bioinspired, Liquid–Liquid Phase Separation of Monomers

S Patra, S Chandrabhas, S Dhiman… - Journal of the American …, 2024 - ACS Publications
Dynamic supramolecular assemblies, driven by noncovalent interactions, pervade the
biological realm. In the synthetic domain, their counterparts, supramolecular polymers …

Metallosupramolecular Multiblock Copolymers of Lanthanide Complexes by Seeded Living Polymerization

S Lim, Y Cho, JH Kang, M Hwang, Y Park… - Journal of the …, 2024 - ACS Publications
Supramolecular block copolymers, derived via seeded living polymerization, are
increasingly recognized for their rich structural and functional diversity, marking them as …

Off–On Pathway Complexity in Self-Assembly of Cadmium Cholate Hydrogel with Topological Evolution Triggered by Secondary Nucleation

M Sahu, I Seth, SJ George, U Maitra - Chemistry of Materials, 2024 - ACS Publications
Tuning supramolecular hierarchical structures based on a meticulous mechanistic
understanding has been a less-explored area of supramolecular chemistry. We have …

Pathway-dependent supramolecular polymerization by planarity breaking

RM Veedu, Z Fernandez, N Bäumer, A Albers… - Chemical …, 2024 - pubs.rsc.org
In controlled supramolecular polymerization, planar π-conjugated scaffolds are commonly
used to predictably regulate stacking interactions, with various assembly pathways arising …

Redox-Regulated In Situ Seed-Induced Assembly of Peptides

X Mo, J Song, X Liu, RC Guo, B Hu, Z Yu - Biomacromolecules, 2024 - ACS Publications
Morphology-transformational self-assembly of peptides allows for manipulation of the
performance of nanostructures and thereby advancing the development of biomaterials …

Amplification and Attenuation of Asymmetry via Kinetically Controlled Seed‐Induced Supramolecular Polymerization

A Das, S Ghosh, SJ George - Angewandte Chemie International … - Wiley Online Library
The amplification of asymmetry in supramolecular polymers has recently garnered
significant attention. While asymmetry amplification has predominantly been explored under …

Hierarchical Self‐Assembly of Hyperbranched Polymer‐Based Topological Supramolecular Amphiphiles

H Zhang, Y Pan, Y Li, C Li, Y Wang, W Jiang… - … –A European Journal - Wiley Online Library
Supramolecular polymers (SPs) are constructed through non‐covalent interactions. The
dynamic or reversible nature of SPs endows them unique physical and chemical properties …