In the present work, the rich chemistry of rhodium/phosphine complexes, which are applied
as homogeneous catalysts to promote a wide range of chemical transformations, has been …

The catalytic C–H borylation of arenes with HBpin (pin= pinacolate) using POCOP-type
pincer complexes of Ir has been demonstrated, with turnover numbers exceeding 10 000 in …

This article describes a well-defined pincer-Rh catalyst for C–S cross-coupling
reactions.(POCOP) Rh (H)(Cl) serves as an active precatalyst for the coupling of aryl …

Rhodium–aluminum bimetallic complexes catalyze the Kumada–Tamao–Corriu (KTC) cross-
coupling reaction using arylmagnesium compounds that are generated from the …

A series of cobalt POCOP pincer complexes with the formulas {2, 6-(iPr2PO) 2-4-R′-C6H2}
Co (CO) 2 (R′= H (1a), NMe2 (1b), OMe (1c), CO2Me (1d)),{2, 6-(Ph2PO) 2C6H3} Co (CO) …

Anionic diarylrhodium complexes, generated by reacting [RhCl (cod)] 2 with 2 equiv of aryl
Grignard reagents, were found to be effective active catalysts in cross-coupling reactions of …

Cobalt POCOP pincer complexes {κP, κC, κP-2, 6-(i Pr2PO) 2C6H3} Co (PMe3) 2 (1) and
{κP, κC, κP-2, 6-(i Pr2PO) 2-4-NMe2-C6H2} Co (PMe3) 2 (2) have been synthesized via C …

A series of pincer complexes of Rh has been prepared and tested as catalysts for the
dimerization of terminal alkynes. The pincers included aryl/bis (phosphinite) POCOP, aryl/bis …

A rhodium-catalysed stitching reaction between 2-(silylethynyl) arylboronates and 2-
(silylethynyl) aryl bromides has been developed for the synthesis of unsymmetric dibenzo [a …

This work follows a previously published study of high-turnover aromatic C–H borylation by
Ir complexes supported by POCOP-type ligands incorporating− PiPr2 side donors (L1–L3) …