Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Supported anionic gold nanoparticle catalysts modified using highly negatively charged multivacant polyoxometalates

K Xia, T Yatabe, K Yonesato, T Yabe… - Angewandte Chemie …, 2022 - Wiley Online Library
Although supported anionic gold nanoparticle catalysts have been theoretically investigated
for their efficacy in activating O2 in aerobic oxidation reactions, limited studies have been …

Development of environmentally friendly dehydrogenative oxidation reactions using multifunctional heterogeneous catalysts

K Yamaguchi, X Jin, T Yatabe… - Bulletin of the Chemical …, 2022 - academic.oup.com
Our design strategies for multifunctional heterogeneous catalysts based on nanosized metal
oxides and metal nanoparticles as well as the development of several novel …

Decarbonylation of 1, 2-Diketones to Diaryl Ketones via Oxidative Addition Enabled by an Electron-Deficient Au–Pd Nanoparticle Catalyst

T Matsuyama, T Yatabe, T Yabe, K Yamaguchi - ACS Catalysis, 2022 - ACS Publications
Decarbonylation via oxidative addition has been widely studied as a challenging and
beneficial transformation using various carbonyl compounds. To our knowledge, however …

Carbocation Mechanism Revelation of Molecular Iodine-Mediated Dehydrogenative Aromatization of Substituted Cyclic Ketones to Phenols

Y Jin, PV Petrovic, S Huang, S Banerjee… - The Journal of …, 2024 - ACS Publications
Dehydrogenative aromatization (DA) of cyclic ketones is central to the development of
functionalized aromatic precursors and hydrogen transfer–related technologies. Traditional …

Design Strategy of Metal Nanoparticle Catalysis for C− H Bond Activation Reactions

S Hasegawa, K Motokura - ChemCatChem, 2024 - Wiley Online Library
C− H bond activation reactions facilitate highly efficient molecular transformations without
requiring pre‐activating substrates. While the majority of reported reaction systems for C− H …

[PDF][PDF] C–S/C–Br metathesis enabled by an Au–Pd alloy nanoparticle catalyst

T Matsuyama, T Yatabe, K Yamaguchi - 2024 - chemrxiv.org
Metathesis via C–S bond oxidative addition and reductive elimination has recently
witnessed considerable development as a functionalization of ubiquitous sulfur-containing …

Ni-catalysed acceptorless dehydrogenative aromatisation of cyclohexanones enabled by concerted catalysis specific to supported nanoparticles

K Yamaguchi, T Yatabe, T Matsuyama, T Yabe - 2024 - researchsquare.com
The dehydrogenative aromatisation of cyclohexanone derivatives has had a transformative
influence on the synthesis of aromatic compounds because functional groups can be easily …

Ni-catalysed acceptorless dehydrogenative aromatisation of cyclohexanone derivatives enabled by concerted catalysis specific to supported nanoparticles

T Matsuyama, T Yatabe, T Yabe, K Yamaguchi - 2024 - chemrxiv.org
The dehydrogenative aromatisation of cyclohexanone derivatives has had a transformative
influence on the synthesis of aromatic compounds because functional groups can be easily …

Heterogeneously Catalyzed Thioether Metathesis by a Supported Au–Pd Alloy Nanoparticle Design Based on Pd Ensemble Control

T Matsuyama, T Yatabe, T Yabe, K Yamaguchi - 2024 - chemrxiv.org
C–S bond metathesis of thioethers has gained attention as a new approach to the late-stage
diversification of already existing useful thioethers with intact molecular frameworks …