Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C–H bonds

JL Roizen, ME Harvey, J Du Bois - Accounts of chemical research, 2012 - ACS Publications
For more than a century, chemists have endeavored to discover and develop reaction
processes that enable the selective oxidation of hydrocarbons. In the 1970s, Abramovitch …

Transition-metal-catalyzed reactions in heterocyclic synthesis

I Nakamura, Y Yamamoto - Chemical reviews, 2004 - ACS Publications
Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis | Chemical Reviews ACS
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Nitrene chemistry in organic synthesis: still in its infancy?

G Dequirez, V Pons, P Dauban - … Chemie International Edition, 2012 - Wiley Online Library
The element nitrogen is essential to life. Considerable attention is thus paid to the
development of synthetic methods for its introduction into molecules. Nitrenes, long …

Catalytic C–H amination: the stereoselectivity issue

F Collet, C Lescot, P Dauban - Chemical Society Reviews, 2011 - pubs.rsc.org
Catalytic C–H amination has recently emerged as a unique tool for the synthesis of amines.
This tutorial review highlights the existing protocols catalyzed by metal complexes (rhodium …

Catalytic methods for metal carbene transformations

MP Doyle - Chemical Reviews, 1986 - ACS Publications
The synthetic uses of organicdiazo compounds for carbenoid transformations have
undergone a renais-sance in recent years as a result of the development of new transition …

Enantioselective catalytic aziridinations and asymmetric nitrene insertions into CH bonds

P Müller, C Fruit - Chemical reviews, 2003 - ACS Publications
Aziridines are the nitrogen analogues of epoxides and exhibit similar reactivity patterns as
electrophilic reagents. 1 They undergo highly regio-and stereoselective transformations and …

<?ACS-CT-START-Insert ?>Update 1 of: <?ACS-CT-END-Insert ?>C2-Symmetric Chiral Bis(oxazoline) Ligands in Asymmetric Catalysis

G Desimoni, G Faita, KA Jørgensen - Chemical Reviews, 2011 - ACS Publications
Asymmetric catalysis with chiral metal complexes has received considerable attention in
recent years, and its contribution to the art of organic synthesis has become of leading …

Hypervalent iodine chemistry in synthesis: Scope and new directions

T Wirth - Angewandte Chemie International Edition, 2005 - Wiley Online Library
The impressive development of hypervalent iodine chemistry in recent years is reflected by
the number of publications in this area. Although the synthesis of the first hypervalent iodine …

Transition metal catalyzed oxidative functionalization of carbon–hydrogen bonds

AR Dick, MS Sanford - Tetrahedron, 2006 - Elsevier
The development of mild, general, and selective transition metal catalyzed methods for the
functionalization of carbon–hydrogen bonds represents a significant current challenge in …

Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

TG Driver - Organic & biomolecular chemistry, 2010 - pubs.rsc.org
Transition metal-catalyzed N-atom transfer reactions of azides provide efficient ways to
construct new carbon–nitrogen and sulfur–nitrogen bonds. These reactions are inherently …