Laboratory studies of organic peroxy radical chemistry: an overview with emphasis on recent issues of atmospheric significance

JJ Orlando, GS Tyndall - Chemical Society Reviews, 2012 - pubs.rsc.org
Organic peroxy radicals (often abbreviated RO2) play a central role in the chemistry of the
Earth's lower atmosphere. Formed in the atmospheric oxidation of essentially every organic …

The reaction kinetics of dimethyl ether. II: Low‐temperature oxidation in flow reactors

HJ Curran, SL Fischer, FL Dryer - International Journal of …, 2000 - Wiley Online Library
Dimethyl ether oxidation has been studied in a variable-pressure flow reactor over an initial
reactor temperature range of 550–850 K, in the pressure range 12–18 atm, at equivalence …

A wide range modeling study of dimethyl ether oxidation

HJ Curran, WJ Pitz, CK Westbrook… - … Journal of Chemical …, 1998 - Wiley Online Library
A detailed chemical kinetic model has been used to study dimethyl ether (DME) oxidation
over a wide range of conditions. Experimental results obtained in a jet‐stirred reactor (JSR) …

Tropospheric oxidation mechanism of dimethyl ether and methyl formate

DA Good, JS Francisco - The Journal of Physical Chemistry A, 2000 - ACS Publications
The oxidation mechanism of dimethyl ether is investigated using ab initio methods. The
structure and energetics of reactants, products, and transition structures are determined for …

A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames

A Mcilroy, TD Hain, HA Michelsen, TA Cool - Proceedings of the …, 2000 - Elsevier
The oxidation of dimethyl ether (DME) was studied in low-pressure, premixed flames using a
new molecular beam mass spectrometer (MBMS) and laser diagnosties. The mass …

Dimethyl Ether Oxidation:  Kinetics and Mechanism of the CH3OCH2 + O2 Reaction at 296 K and 0.38−940 Torr Total Pressure

J Sehested, T Møgelberg, TJ Wallington… - The Journal of …, 1996 - ACS Publications
The title reaction was studied at 296 K and 0.38− 940 Torr total pressure using a FTIR smog
chamber technique. The overall rate constant for reaction of CH3OCH2 radicals with O2 may …

Dimethyl ether oxidation at elevated temperatures (295− 600 K)

CM Rosado-Reyes, JS Francisco… - The Journal of …, 2005 - ACS Publications
Dimethyl ether (DME) has been proposed for use as an alternative fuel or additive in diesel
engines and as a potential fuel in solid oxide fuel cells. The oxidation chemistry of DME is a …

Oxidation of dimethyl ether: absolute rate constants for the self reaction of CH3OCH2 radicals, the reaction of CH3OCH2 radicals with O2, and the thermal …

J Sehested, K Sehested, J Platz… - … journal of chemical …, 1997 - Wiley Online Library
The rate constant for the reaction of CH3OCH2 radicals with O2 (reaction (1)) and the self
reaction of CH3OCH2 radicals (reaction (5)) were measured using pulse radiolysis coupled …

Atmospheric chemistry of dimethoxymethane (CH3OCH2OCH3): Kinetics and mechanism of its reaction with OH radicals and fate of the alkoxy radicals CH3OCHO (•) …

TJ Wallington, MD Hurley, JC Ball… - The Journal of …, 1997 - ACS Publications
The rate constant for the reaction of dimethoxymethane (DMM) with OH radicals was
determined to be (4.6±1.6)× 10-12 at 346±3 K using a pulse radiolysis/transient UV …

Kinetics and mechanism of the reactions between triphenylphosphine, dialkyl acetylenedicarboxilates and a NH-acid, pyrazole, by UV spectrophotometry

SM Habibi Khorassani, MT Maghsoodlou… - Journal of solution …, 2007 - Springer
Kinetic studies were made of the reactions between triphenylphosphine and dialkyl
acetylenedicarboxylates in the presence of a NH-acid such as pyrazole. To determine the …