Electrochemical strategies for C–H functionalization and C–N bond formation

MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …

Visible light promoted cross-dehydrogenative coupling: a decade update

AK Bagdi, M Rahman, D Bhattacherjee… - Green …, 2020 - pubs.rsc.org
The visible light promoted cross-dehydrogenative coupling reaction has emerged as an
excellent strategy for the direct formation of C–C/C–heteroatom bonds from simple …

Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

SK Parida, T Mandal, S Das, SK Hota, S De Sarkar… - ACS …, 2021 - ACS Publications
The past decade has witnessed the emergence of N-(acyloxy) phthalimides (NHPI esters)
and its derivatives at the forefront of synthetic methods facilitating the construction of diverse …

N‐(Acyloxy)phthalimides as Redox‐Active Esters in Cross‐Coupling Reactions

S Murarka - Advanced Synthesis & Catalysis, 2018 - Wiley Online Library
Recent years have witnessed a resurgence of novel, efficient and practical protocols for
radical‐mediated cross‐coupling reactions involving N‐(acyloxy) phthalimides (NHPI esters) …

Emerging Trends in Copper-Promoted Radical-Involved C–O Bond Formations

PZ Wang, JR Chen, WJ Xiao - Journal of the American Chemical …, 2023 - ACS Publications
The C–O bond is ubiquitous in biologically active molecules, pharmaceutical agents, and
functional materials, thereby making it an important functional group. Consequently, the …

En route to intermolecular cross-dehydrogenative coupling reactions

CY Huang, H Kang, J Li, CJ Li - The Journal of Organic Chemistry, 2019 - ACS Publications
Cross-coupling reaction between two C–H bonds has become a fundamental strategy in
synthetic organic chemistry. With its increasing importance in green chemistry, atom …

Transition‐Metal‐Catalyzed Utilization of Methanol as a C1 Source in Organic Synthesis

K Natte, H Neumann, M Beller… - Angewandte Chemie …, 2017 - Wiley Online Library
Methanol is used as a common solvent, cost‐effective reagent, and sustainable feedstock for
value‐added chemicals, pharmaceuticals, and materials. Among the various applications …

Cyclic Diaryl λ3-Chloranes: Reagents and Their C–C and C–O Couplings with Phenols via Aryne Intermediates

M Lanzi, T Rogge, TS Truong, KN Houk… - Journal of the …, 2022 - ACS Publications
Hypervalent chloranes are a class of rare and poorly explored reagents. Their unique
electronic properties confer reactivity that is complementary to that of the common iodanes …

Metal-involving synthesis and reactions of oximes

DS Bolotin, NA Bokach, MY Demakova… - Chemical …, 2017 - ACS Publications
This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …

Cobalt‐Catalyzed C− H Thiolation through Dehydrogenative Cross‐Coupling

T Gensch, FJR Klauck, F Glorius - … Chemie International Edition, 2016 - Wiley Online Library
A cobalt‐catalyzed dehydrogenative cross‐coupling of thiols and indoles is reported. Using
a cooperative reaction system, a new mode of action for the cobalt‐catalyzed C− heteroatom …