Molecules with permanent porosity in the solid state have been studied for decades.
Porosity in these systems is governed by intrinsic pore space, as in cages or macrocycles …

The pollution due to the presence of contaminants of emerging concern (CECs) is a major
cause for concern because of the serious threat it supposes to human health and ecosystem …

The accurate identification of catalytic sites in heterogeneous catalysts poses a significant
challenge due to the intricate nature of controlling interfacial chemistry at the molecular …

The preparation and rational design of nanosized clusters (M n) and cages based on the
macrocyclic thiacalix [4] arene backbone in cone conformation has been analysed in the …

Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix
[4] arene-supported tetranuclear M (II) clusters (M= Co, Ni) with hybrid linker based on tris …

The unique high surface area and tunable cavity size endow metal–organic cages (MOCs)
with superior performance and broad application in gas adsorption and separation. Over the …

Among all porous materials, permanently porous metal–organic architectures offer
unparalleled structural diversity and tunability that has led to their extensive development …

Functionalization of permanently porous coordination cages has been used to tune phase,
surface area, stability, and solubility in this promising class of adsorbents. For many cages …

Ligand functionalization has been thoroughly leveraged to alter the properties of
paddlewheel-based coordination cages where, in the case of ligand-terminated cages …

A useful correlation between the low-pressure (up to 1.2 bar), low-temperature (195 K) and
high-pressure (up to 65 bar), room temperature (298 K) methane storage properties of a …