Energy-efficient separation alternatives: metal–organic frameworks and membranes for hydrocarbon separation

L Yang, S Qian, X Wang, X Cui, B Chen… - Chemical Society …, 2020 - pubs.rsc.org
Hydrocarbon separation is one of the most critically important and complex industrial
separation processes, offering versatile bulk chemicals and vital support to the national …

Separation and purification of hydrocarbons with porous materials

Y Wu, BM Weckhuysen - Angewandte Chemie International …, 2021 - Wiley Online Library
This Minireview focuses on the developments of the adsorptive separation of
methane/nitrogen, ethene/ethane, propene/propane mixtures as well as on the separation of …

A Microporous Metal‐Organic Framework with Unique Aromatic Pore Surfaces for High Performance C2H6/C2H4 Separation

Y Ye, Y Xie, Y Shi, L Gong, J Phipps… - Angewandte …, 2023 - Wiley Online Library
Developing adsorptive separation processes based on C2H6‐selective sorbents to replace
energy‐intensive cryogenic distillation is a promising alternative for C2H4 purification from …

One‐Step C2H4 Purification from Ternary C2H6/C2H4/C2H2 Mixtures by a Robust Metal–Organic Framework with Customized Pore Environment

GD Wang, YZ Li, WJ Shi, L Hou… - Angewandte Chemie …, 2022 - Wiley Online Library
One‐step C2H4 purification from ternary C2H6/C2H4/C2H2 mixtures by a single adsorbent
is of great industrial significance, but few adsorbents achieve this separation. Herein, we …

Rational design and synthesis of ultramicroporous metal-organic frameworks for gas separation

T Wang, E Lin, YL Peng, Y Chen, P Cheng… - Coordination Chemistry …, 2020 - Elsevier
Metal-organic frameworks (MOFs) have emerged as a new generation of porous materials
that demonstrate great promise in diverse application fields, especially gas separation, due …

Recent advances in metal–organic frameworks for gas adsorption/separation

C Jiang, X Wang, Y Ouyang, K Lu, W Jiang, H Xu… - Nanoscale …, 2022 - pubs.rsc.org
The unique structural advantage of metal–organic frameworks (MOFs) determines the great
prospect and developability in gas adsorption and separation. Both ligand design and …

Pore-space-partition-enabled exceptional ethane uptake and ethane-selective ethane–ethylene separation

H Yang, Y Wang, R Krishna, X Jia… - Journal of the …, 2020 - ACS Publications
An ideal material for C2H6/C2H4 separation would simultaneously have the highest C2H6
uptake capacity and the highest C2H6/C2H4 selectivity. But such material is elusive. A …

A rod‐packing hydrogen‐bonded organic framework with suitable pore confinement for benchmark ethane/ethylene separation

X Zhang, JX Wang, L Li, J Pei, R Krishna… - Angewandte Chemie …, 2021 - Wiley Online Library
For the separation of ethane from ethylene, it remains challenging to target both high C2H6
adsorption and selectivity in a C2H6‐selective material. Herein, we report a reversible solid …

Reverse-selective metal–organic framework materials for the efficient separation and purification of light hydrocarbons

SQ Yang, TL Hu - Coordination Chemistry Reviews, 2022 - Elsevier
The separation and purification process of hydrocarbons is one of the crucial and daunting
challenges in the petrochemistry field, which is widely depended on cryogenic distillation by …

Construction of Fluorinated Propane‐Trap in Metal–Organic Frameworks for Record Polymer‐Grade Propylene Production under High Humidity Conditions

Y Wang, T Li, L Li, RB Lin, X Jia, Z Chang… - Advanced …, 2023 - Wiley Online Library
Abstract Propane/propene (C3H8/C3H6) separation is essential in the petrochemical
industry but challenging because of their similar physical and chemical properties …