Mechanistic insights into the thermal decomposition of ammonia borane, a material studied for chemical hydrogen storage

UB Demirci - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
Though ammonia borane NH3BH3 (AB) was discovered in the 1950s, it is fair to state that
AB as a potential chemical hydrogen storage material was discovered more recently, in the …

Rerouting pathways of solid-state ammonia borane energy release

P Biswas, P Ghildiyal, H Kwon, H Wang… - The Journal of …, 2021 - ACS Publications
Ammonia borane (NH3BH3, AB) represents a promising energy-dense material for
hydrogen storage and propulsion; however, its energy release mechanisms on oxidation by …

Catalytic Cleavage of the Dative Bond of Ammonia Borane by Polymeric Carbonyl Groups for Enhanced Energy Generation

P Biswas, Y Wang, S Herrera, P Ghildiyal… - Chemistry of …, 2023 - ACS Publications
Dissociation of the dative (B–N) bond of ammonia borane (NH3BH3/AB) is essential to
prevent its thermochemical oligomerization to chemically resistant BNH x compounds, for its …

Thermolytic decomposition of ethane 1, 2-diamineborane investigated by thermoanalytical methods and in situ vibrational spectroscopy

F Leardini, MJ Valero-Pedraza… - The Journal of …, 2014 - ACS Publications
Ethane 1, 2-diamineborane (BH3NH2CH2CH2NH2BH3, EDAB hereafter) samples have
been synthesized by reacting ethylenediamine dihydrochloride with sodium borohydride in …

Hydrogen generation from ammonia borane and water through combustion reactions with mechanically alloyed Al· Mg powder

DA Rodriguez, EL Dreizin, E Shafirovich - Combustion and Flame, 2015 - Elsevier
It is known that ammonia borane (AB) forms combustible mixtures with gelled water and
nanoscale aluminum powder. The reaction of nanoaluminum with water serves as a source …

Sublimation and thermal decomposition of ammonia borane: Competitive processes controlled by pressure

YV Kondrat'ev, AV Butlak, IV Kazakov, AY Timoshkin - Thermochimica Acta, 2015 - Elsevier
Thermal behavior of ammonia borane BH 3 NH 3 (AB) has been studied by calorimetry,
tensimetry and mass spectrometry methods. It is shown, that depending on vapor pressure …

Improvement of the kinetics of hydrogen release from ammonia borane confined in silica aerogel

M Rueda, LM Sanz-Moral, JJ Segovia… - … and Mesoporous Materials, 2017 - Elsevier
Ammonia borane is a promising hydrogen storage material due to its high gravimetric
capacity (19.6% wt), but it also presents limitations such as a slow hydrogen release with a …

Production of silica aerogel microparticles loaded with ammonia borane by batch and semicontinuous supercritical drying techniques

M Rueda, LM Sanz-Moral, A Nieto-Márquez… - The Journal of …, 2014 - Elsevier
Silica aerogel microparticles were prepared by supercritical drying and used as support for
hydrogen-storing ammonia borane (AB). The formation of aerogel microparticles was done …

Dehydrogenation of ammonia borane recrystallized by different techniques

OV Komova, VI Simagina, VR Butenko, GV Odegova… - Renewable Energy, 2022 - Elsevier
Annotation The literature shows that practically no attention has been paid to the size and
shape of the particles of bulk ammonia borane (NH 3 BH 3). The published results about the …

Discrepancy in the thermal decomposition/dehydrogenation of ammonia borane screened by thermogravimetric analysis

JF Petit, UB Demirci - International Journal of Hydrogen Energy, 2019 - Elsevier
Abstract Ammonia borane NH 3 BH 3 (AB), in pristine or destabilized state, has been much
investigated as a solid-state chemical hydrogen storage material. The potential of such …