Combustion chemistry of alkenes and alkadienes
Alkenes formed, during the refining of crude oil, by cracking the heavier fractions are present
in transportation fuels in significant amounts, up to as much as 15–20% in gasoline …
in transportation fuels in significant amounts, up to as much as 15–20% in gasoline …
Review of oxidation of gasoline surrogates and its components
There has been considerable progress in the area of fuel surrogate development to emulate
gasoline fuels' oxidation properties. The current paper aims to review the relevant …
gasoline fuels' oxidation properties. The current paper aims to review the relevant …
A theoretical calculation and kinetic modeling analysis of H-abstraction from 1-octene for subsequent isomerization and β-dissociation
J Yan, P Wang, T Yan, C Ao, L Zhang, L Lei - International Journal of …, 2024 - Elsevier
As a main component of alkenes, 1-octene is the key important intermediate in the process
of oxidation or pyrolysis of n-decane or higher alkanes. In this work, quantum chemistry …
of oxidation or pyrolysis of n-decane or higher alkanes. In this work, quantum chemistry …
Development of a 5-component gasoline surrogate model using recent advancements in the detailed H2/O2/CO/C1-C3 mechanism for decoupling methodology
In the present work, a 5-component gasoline surrogate chemical kinetic mechanism has
been developed and validated. The first novelty of this mechanism is that a recently …
been developed and validated. The first novelty of this mechanism is that a recently …
Potential of derivation of a series of C6–C14 1-alkene skeletal oxidation mechanisms on the basis of reaction rate rules
Olefins, accounting for one-fifth proportion of gasoline fuel, are also essential intermediates
in the combustion of large hydrocarbons and vital precursors of large polycyclic aromatic …
in the combustion of large hydrocarbons and vital precursors of large polycyclic aromatic …
Reaction Mechanisms and Kinetics of the Hydrogen Abstraction Reactions of C4–C6 Alkenes with Hydroxyl Radical: A Theoretical Exploration
QD Wang, MM Sun, JH Liang - International journal of molecular sciences, 2019 - mdpi.com
The reaction of alkenes with hydroxyl (OH) radical is of great importance to atmospheric and
combustion chemistry. This work used a combined ab initio/transition state theory (TST) …
combustion chemistry. This work used a combined ab initio/transition state theory (TST) …
Kinetics of hydrogen abstraction and addition reactions of 3-hexene by OH radicals
Rate coefficients of H atom abstraction and H atom addition reactions of 3-hexene by the
hydroxyl radicals were determined using both conventional transition-state theory and …
hydroxyl radicals were determined using both conventional transition-state theory and …
Measurement of laminar flame speed and chemical kinetic model of 1-pentene/air mixtures
BJ Zhong, HS Peng - Combustion Science and Technology, 2017 - Taylor & Francis
Pentene is the main composition of alkene in practical gasolines. Laminar flame speeds of 1-
pentene/air were measured in a constant volume combustion bomb at initial pressures of 0.1 …
pentene/air were measured in a constant volume combustion bomb at initial pressures of 0.1 …
Experimental and kinetic study on laminar flame speeds of hexene isomers and n-hexane
Laminar flame speeds of hexene isomers (1-hexene, 2-hexene and 3-hexene) and n-
hexane are investigated at equivalence ratios of 0.8–1.5, initial temperatures of 373–453 K …
hexane are investigated at equivalence ratios of 0.8–1.5, initial temperatures of 373–453 K …
The kinetic model of cyclohexene–air combustion over a wide temperature range
H Lu, W Kong, C Zhang, J Wang, X Li - RSC advances, 2021 - pubs.rsc.org
Cyclohexene is an important intermediate during the combustion process of hydrocarbon
and oxygenated fuels. In view of the lack of study on the combustion of cyclohexene in air …
and oxygenated fuels. In view of the lack of study on the combustion of cyclohexene in air …