Amphoteric reactivity of metal–oxygen complexes in oxidation reactions

M Sankaralingam, YM Lee, W Nam… - Coordination Chemistry …, 2018 - Elsevier
Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …

Microporous metal− organic frameworks formed in a stepwise manner from luminescent building blocks

BD Chandler, DT Cramb… - Journal of the American …, 2006 - ACS Publications
A series of trivalent lanthanides (Sm, Eu, Gd, Tb, Dy) have been complexed to the dianionic
ligand, 4, 4 '-disulfo-2, 2 '-bipyridine-N, N '-dioxide, L, in a 3: 1 ratio to form trianionic complex …

Beyond carbocations: Synthesis, structure and reactivity of heavier Group 14 element cations

H Fang, Z Wang, X Fu - Coordination Chemistry Reviews, 2017 - Elsevier
Carbocations represent one of the most active organic compounds. Many efforts have been
paid in extending the chemistry of carbocations down the group to the heavier elements (Si …

Synthesis of One- and Two-Dimensional Coordination Polymers Containing Organotin Macrocycles. Reactions of (n-Bu3Sn)2O with Pyridine Dicarboxylic Acids …

V Chandrasekhar, C Mohapatra… - Crystal growth & …, 2012 - ACS Publications
The reaction of (n-Bu3Sn) 2O with pyridine-2, 6-dicarboxylic acid (L1H 2) in a 1: 1 ratio
resulted in the formation of a one-dimensional (1D) coordination polymer [(n-Bu3Sn) 2 (n …

Silver (I) arylsulfonates: a systematic study of “softer” hybrid inorganic− organic solids

AP Côté, GKH Shimizu - Inorganic chemistry, 2004 - ACS Publications
The present study represents the first systematic examination of the effects on the layered
structure of simple silver aryl− monosulfonates as the breadth of the pendant aryl group is …

Structural constraints in the design of silver sulfonate coordination networks: three new polysulfonate open frameworks

DJ Hoffart, SA Dalrymple, GKH Shimizu - Inorganic chemistry, 2005 - ACS Publications
Three new silver sulfonate metal− organic frameworks are presented along with a design
strategy for future generations.{[Ag6 (mesitylenetrisulfonate) 2 (H2O) 5]⊙ 2H2O}∞(1),{Ag4 …

Solventless reactions for the synthesis of organotin clusters and cages

V Chandrasekhar, V Baskar, R Boomishankar… - …, 2003 - ACS Publications
Organotin clusters and cages have been synthesized in quantitative yields by using a
benign solventless synthetic methodology. Using this method a variety of structural forms …

Approach to Di/Triorganotin (IV) Cations via Hydrolysis of Stannate Salts Bearing Alkanesulfonate Ligands

R Shankar, P Chauhan, E Jakhar, A Dubey… - Inorganic …, 2023 - ACS Publications
An in-depth study of the class of organotin cations bearing weakly coordinating
trifluoromethanesulfonate/arylsulfonate has led to key insights into their stability, structural …

Chromiumpentacarbonyl-coordinated organotin (II) cation

R Dostálová, L Dostál, A Růžička… - Organometallics, 2011 - ACS Publications
The synthesis of the novel chromiumpentacarbonyl complex [2, 6-(MeOCH2) 2C6H3](Cl)
SnCr (CO) 5 (1) is reported. Compound 1 was used for the synthesis of novel …

First Example of a Hydrogen-Bonded Three-Dimensional Pillared Structure Involving an Organotin Motif:  Synthesis and X-ray Crystal Structures of {[nBu2Sn(H2O)3(L)Sn(H2O)3nBu2]2+[L]2-}·2MeOH·2H2O and …

V Chandrasekhar, R Boomishankar, A Steiner… - …, 2003 - ACS Publications
The reaction of a disulfonic acid with n Bu3SnOSn n Bu3 generates the Sn− alkyl-cleaved
dicationic species {[n Bu2Sn (H2O) 3 (L) Sn (H2O) 3 n Bu2] 2+[L] 2-}⊙ 2MeOH⊙ 2H2O (4; …