Beyond charge balance: counter‐cations in polyoxometalate chemistry

A Misra, K Kozma, C Streb… - Angewandte Chemie …, 2020 - Wiley Online Library
Polyoxometalates (POMs) are molecular metal‐oxide anions applied in energy conversion
and storage, manipulation of biomolecules, catalysis, as well as materials design and …

Jenseits von Ladungsausgleich: Gegenkationen in der Polyoxometallat‐Chemie

A Misra, K Kozma, C Streb, M Nyman - Angewandte Chemie, 2020 - Wiley Online Library
Abstract Polyoxometallate (POMs) sind molekulare Metalloxidanionen, die Anwendung in
Energiewandlung und‐speicherung, biomolekularer Chemie sowie Materialdesign und …

Captivation with encapsulation: a dozen years of exploring uranyl peroxide capsules

PC Burns, M Nyman - Dalton Transactions, 2018 - pubs.rsc.org
Uranyl peroxide clusters containing from 16 to 124 uranyl ions self-assemble in aqueous
solution and exhibit tremendous topological complexity. Most of these clusters are cages …

Structural diversity of bipyridinium-based uranyl coordination polymers: Synthesis, characterization, and ion-exchange application

LW Zeng, KQ Hu, L Mei, FZ Li, ZW Huang… - Inorganic …, 2019 - ACS Publications
As well-known functional groups with excellent electro/photochromic and ion-exchange
properties, bipyridinium motifs have been used in functionalized metal–organic coordination …

Guard Cell‐Inspired Ion Channels: Harnessing the Photomechanical Effect via Supramolecular Assembly of Cross‐Linked Azobenzene/Polymers

YF Chen, CL Hsieh, PY Lin, YC Liu, MJ Lee, LR Lee… - Small, 2024 - Wiley Online Library
Stimuli‐responsive ion nanochannels have attracted considerable attention in various fields
because of their remote controllability of ionic transportation. For photoresponsive ion …

Novel viologen derivative based uranyl coordination polymers featuring photochromic behaviors

KQ Hu, QY Wu, L Mei, XL Zhang, L Ma… - … A European Journal, 2017 - Wiley Online Library
A series of novel uranyl coordination polymers have been synthesized by hydrothermal
reactions. Both complexes 1 and 2 prosess two ipbp− ligands (H2ipbpCl= 1‐(3, 5 …

Strong co-ion effect via cation− π interaction on the self-assembly of metal–organic cationic macrocycles

B Qi, X Guo, Y Gao, D Li, J Luo, H Li… - Journal of the …, 2017 - ACS Publications
The predesigned metal–organic macrocycle Zn3QDB3 (NO3) 4 (Zn-QDB) was observed to
self-assemble into a hollow, spherical, single-layered “blackberry”-type structure. The self …

Rationally controlling the self-assembly behavior of triarmed POSS–organic hybrid macromolecules: from giant surfactants to macroions

W Zhang, Y Chu, G Mu, SA Eghtesadi, Y Liu… - …, 2017 - ACS Publications
Two triarmed organic–inorganic hybrid materials based on carboxylic acid-functionalized
polyhedral oligomeric silsesquioxane (APOSS) with/without PS linkers are designed and …

Expanding the Schulze–Hardy Rule and the Hofmeister Series to Nanometer‐Scaled Hydrophilic Macroions

Y Chu, J Chen, F Haso, Y Gao… - … A European Journal, 2018 - Wiley Online Library
Abstract The Schulze–Hardy rule is a well‐established observation in colloid science (can
be derived from the DLVO theory) that demonstrates the relationship between the critical …

Accurate determination of the quantity and spatial distribution of counterions around a spherical macroion

J Chen, MK Bera, H Li, Y Yang, X Sun… - Angewandte Chemie …, 2021 - Wiley Online Library
The accurate distribution of countercations (Rb+ and Sr2+) around a rigid, spherical, 2.9‐nm
size polyoxometalate cluster,{Mo132} 42−, is determined by anomalous small‐angle X‐ray …