Full optimization of dynamic nuclear polarization on a 1 tesla benchtop polarizer with hyperpolarizing solids

E Vaneeckhaute, C Bocquelet, L Bellier… - Physical Chemistry …, 2024 - pubs.rsc.org
Hyperpolarization by dissolution dynamic nuclear polarization (dDNP) provides the
opportunity to dramatically increase the weak nuclear magnetic resonance (NMR) signal of …

In DNP mechanisms

K Kundu, F Mentink-Vigier, A Feintuch… - Handbook of High Field …, 2019 - books.google.com
In this chapter, we have attempted to present a comprehensive description of the spin
dynamics leading to the nuclear signal enhancements observed during dynamic nuclear …

13C Dynamic Nuclear Polarization using SA-BDPA at 6.7 T and 1.1 K: Coexistence of Pure Thermal Mixing and Well-Resolved Solid Effect

A Radaelli, HAI Yoshihara, H Nonaka… - The journal of …, 2020 - ACS Publications
SA-BDPA is a water-soluble, narrow-line width radical previously used for dynamic nuclear
polarization (DNP) signal enhancement in solid-state magic angle spinning NMR …

Dynamic nuclear polarization via the cross effect and thermal mixing: B. Energy transport

WT Wenckebach - Journal of Magnetic Resonance, 2019 - Elsevier
The fundamental process of dynamic nuclear polarization (DNP) via the cross effect (CE)
and thermal mixing (TM) is a triple spin flip, in which two interacting electron spins and a …

Monte Carlo study of the spin-spin interactions between radicals used for dynamic nuclear polarization

WT Wenckebach, Y Quan - Journal of Magnetic Resonance, 2021 - Elsevier
The spectrum of the electron spin-spin interactions largely determines which mechanism is
responsible for the growth of the nuclear spin polarization in dynamic nuclear polarization …

Theoretical aspects of the cross effect enhancement of nuclear polarization under static dynamic nuclear polarization conditions

K Kundu, A Feintuch, S Vega - The journal of physical chemistry …, 2019 - ACS Publications
In this study, we perform quantum calculations of the spin dynamics of a small spin system
that includes nine coupled electrons and one nucleus placed in an external magnetic field …

Spectral diffusion of electron spin polarization in glasses doped with radicals for DNP

WT Wenckebach - Journal of Magnetic Resonance, 2024 - Elsevier
Spectral diffusion of electron spin polarization plays a key part in dynamic nuclear
polarization (DNP). It determines the distribution of polarization across the electron spin …

[HTML][HTML] Unified understanding of the breakdown of thermal mixing dynamic nuclear polarization: The role of temperature and radical concentration

LM Epasto, T Maimbourg, A Rosso… - Journal of Magnetic …, 2024 - Elsevier
We reveal an interplay between temperature and radical concentration necessary to
establish thermal mixing (TM) as an efficient dynamic nuclear polarization (DNP) …

Directly Bound Deuterons Increase X‐Nuclei Hyperpolarization using Dynamic Nuclear Polarization

CHE Rooney, A Gamliel, D Shaul, DJ Tyler… - …, 2023 - Wiley Online Library
Deuterated 13C sites in sugars (D‐glucose and 2‐deoxy‐D‐glucose) showed 6.3‐to‐17.5‐
fold higher solid‐state dynamic nuclear polarization (DNP) levels than their respective …

Brute-force solvent suppression for DNP studies of powders at natural isotopic abundance

P Thureau, M Juramy, F Ziarelli, S Viel… - Solid State Nuclear …, 2019 - Elsevier
A method based on highly concentrated radical solutions is investigated for the suppression
of the NMR signals arising from solvents that are usually used for dynamic nuclear …