Dithiocarbamate complexes as single source precursors to nanoscale binary, ternary and quaternary metal sulfides

JC Sarker, G Hogarth - Chemical Reviews, 2021 - ACS Publications
Nanodimensional metal sulfides are a developing class of low-cost materials with potential
applications in areas as wide-ranging as energy storage, electrocatalysis, and imaging. An …

Metal complexes of alkyl-aryl dithiocarbamates: Structural studies, anticancer potentials and applications as precursors for semiconductor nanocrystals

FP Andrew, PA Ajibade - Journal of Molecular Structure, 2018 - Elsevier
Dithiocarbamates are versatile ligands able to stabilize wide range of metal ions in their
various oxidation states with the partial double bond character of C single bondN and …

[HTML][HTML] Synthesis, X-ray crystal structures and anticancer studies of four Pd (II) dithiocarbamate complexes

AM Paca, PA Ajibade, FP Andrew, N Nundkumar… - Arabian Journal of …, 2021 - Elsevier
Abstract Bis (piperidinyldithiocarbamato) palladium (II)([Pd (Pipdtc) 2]), bis (1-
phenylpiperazinyldithiocarbamato) palladium (II)[Pd (1-PhPzdtc) 2], bis …

Synthesis, optical, and structural studies of iron sulphide nanoparticles and iron sulphide hydroxyethyl cellulose nanocomposites from bis-(dithiocarbamato) iron (ii) …

AM Paca, PA Ajibade - Nanomaterials, 2018 - mdpi.com
In this study, Fe (II) complexes of phenyldithiocarbamate, dimethyldithiocarbamate and
imidazolyldithiocarbamate were used as single-source precursors to prepare iron sulphide …

Optical and structural-chemistry of SnS nanocrystals prepared by thermal decomposition of bis (N-di-isopropyl-N-octyl dithiocarbamato) tin (II) complex for promising …

EL Meyer, JZ Mbese, MA Agoro, R Taziwa - Optical and Quantum …, 2020 - Springer
Mixed ligand precursor complex bis (N-di-isopropyl-N-octyl dithiocarbamato) tin (II) complex
was synthesized from its respective dithiocarbamate ligands, characterized and thermalized …

Synthesis and crystal structure of bis (morpholino dithiocarbamato) Cd (II) complex and its use as precursor for CdS quantum dots using different capping agents

LLR Mphahlele, PA Ajibade - Journal of Sulfur Chemistry, 2019 - Taylor & Francis
Cadmium (II) morpholine dithiocarbamate complex [Cd (morphdtc) 2] was synthesized and
characterized by single crystal X-ray crystallography. The molecular structure of the complex …

Structural, optical and photocatalytic studies of hexadecylamine-capped lead sulfide nanoparticles

AE Oluwalana, PA Ajibade - International Journal of Industrial Chemistry, 2020 - Springer
Hexadecylamine-capped PbS nanoparticles were prepared from lead (II) complexes of
dibenzyl dithiocarbamate (Dibzydtc)[PbS 1], imidazolyl dithiocarbamate (Imdtc)[PbS 2], 2 …

Palladium (ii)-complexes of bi-and tri-dentate phosphine ligands: precursor for palladium–phosphorous nanoparticles and activity towards Suzuki–Miyaura coupling

GK Rao, A Dutta, N Yadav, P Oswal, A Kumar… - New Journal of …, 2023 - pubs.rsc.org
Crystalline Pd7P3 and Pd3P0. 8 nanoparticles (NPs) formed when palladium (II)-complexes
(1 and 2) of (P, N) ligand [3-(diphenylphosphino) propan-1-amine] L1 and (P, N, O−) ligand …

The Effects of Temperature on Iron Sulfide Nanocrystals Prepared from Thermal Decomposition of Bis-(N-methylbenzyldithiocarbamato)iron(II) Complex

PA Ajibade, AM Paca - Journal of Inorganic and Organometallic Polymers …, 2020 - Springer
Abstract Bis-(N-methylbenzyldithiocarbamato) iron (II) complex was thermolyzed at 120, 180
and 240° C to investigate the effects of temperature on the structural and optical properties …

Synthesis, spectroscopic and electrochemical study of Mn (II) complexes of N-methylbenzyl, phenylpiperazyl-and morpholinyl-dithiocarbamate

FP Andrew, PA Ajibade - International Journal of Electrochemical Science, 2019 - Elsevier
Mn (II) complexes of N-methylbenzyl-(L1), phenylpiperazyl-(L2) and morpholinyl-(L3)
dithiocarbamates formulated as [Mn (L1) 2] 1,[Mn (L2) 2] 2 and [Mn (L3) 2] 3 were …