Stability and nature of the volume collapse of ε-Fe2O3 under extreme conditions

JA Sans, V Monteseguro, G Garbarino, M Gich… - Nature …, 2018 - nature.com
Iron oxides are among the major constituents of the deep Earth's interior. Among them, the
epsilon phase of Fe2O3 is one of the less studied polymorphs and there is a lack of …

Spin transition of ferric iron in Al-bearing Mg–perovskite up to 200 GPa and its implication for the lower mantle

K Fujino, D Nishio-Hamane, Y Seto, N Sata… - Earth and Planetary …, 2012 - Elsevier
There are still large discrepancies among the previous reports on the spin transition of iron
in Mg–perovskite (Pv). To alleviate this problem, we examined the spin state of Fe3+ in Mg0 …

Oxidation state of the lower mantle: In situ observations of the iron electronic configuration in bridgmanite at extreme conditions

I Kupenko, C McCammon, R Sinmyo… - Earth and Planetary …, 2015 - Elsevier
We have investigated the electronic configuration of iron in Fe-, Al-containing magnesium
silicate perovskite, ie, bridgmanite, the main component of the lower mantle, at conditions of …

Iron spin state in silicate perovskite at conditions of the Earth's deep interior

C McCammon, K Glazyrin, A Kantor, I Kantor… - High Pressure …, 2013 - Taylor & Francis
We present a review of our recent work concerning the spin state of Fe2+ and Fe3+ in iron
magnesium aluminium silicate perovskite, the most abundant phase in the Earth's interior …

Composition dependence of spin transition in (Mg,Fe)SiO3 bridgmanite

SM Dorfman, J Badro, P Rueff, P Chow, Y Xiao… - American …, 2015 - degruyter.com
Abstract Spin transitions in (Mg, Fe) SiO3 bridgmanite have important implications for the
chemistry and dynamics of Earth's lower mantle, but have been complex to characterize in …

Spectroscopic evidence for the Fe3+ spin transition in iron-bearing δ-AlOOH at high pressure

X Su, C Zhao, L Xu, C Lv, X Song… - … : Journal of Earth …, 2021 - pubs.geoscienceworld.org
Abstract δ-AlOOH has emerged as a promising candidate for water storage in the lower
mantle and could have delivered water into the bottom of the mantle. To date, it still remains …

Mg1-xFexSiO3 (Synthesized Under Pressure)

Y Kawazoe, T Kanomata, R Note - … Properties of Oxides Under Pressure: A …, 2023 - Springer
Mg1-x Fex SiO3 (Synthesized Under Pressure) Page 1 Mg1-x Fex SiO3 (Synthesized Under
Pressure) The orthorhombic perovskite MgSiO3 (x ¼ 0) was synthesized at about 280 kbar …

Synchrotron radiation applications on high-pressure research

B Zou, K Wang, S Li, G Zou - Synchrotron Radiation Applications, 2018 - World Scientific
As an important and matured experimental technology to probing materials' structure,
synchrotron radiation attracts huge amount of users including condensed-matter physicists …

Role of Spin Crossover and Other Physicochemical Transformations in the Lower Mantle

FV Kaminsky, FV Kaminsky - The Earth's Lower Mantle: Composition and …, 2017 - Springer
Extremely high P–T conditions in the lower mantle affect some basic physicochemical
properties of elements in minerals. One of the most important is a spin transition, which …

[图书][B] Portable laser-heating system for experiments with diamond anvil cells and its application to studies of geophysically important materials

I Kupenko - 2014 - search.proquest.com
Untersuchungen unter extremen Bedingungen sind ein wichtiges Hilfsmittel bei der
Herstellung neuer Materialien und deren Charakterisierung hinsichtlich der physikalischen …