Vibrational spectroscopy of ionic liquids

VH Paschoal, LFO Faria, MCC Ribeiro - Chemical reviews, 2017 - ACS Publications
Vibrational spectroscopy has continued use as a powerful tool to characterize ionic liquids
since the literature on room temperature molten salts experienced the rapid increase in …

Solvent nanostructure, the solvophobic effect and amphiphile self-assembly in ionic liquids

TL Greaves, CJ Drummond - Chemical Society Reviews, 2013 - pubs.rsc.org
The ability of ionic liquids (ILs) to support amphiphile self-assembly into a range of
mesophase structures has been established as a widespread phenomenon. From the ILs …

Nanostructured protic ionic liquids retain nanoscale features in aqueous solution while precursor Brønsted acids and bases exhibit different behavior

TL Greaves, DF Kennedy… - The Journal of …, 2011 - ACS Publications
Small-and wide-angle X-ray scattering (SWAXS) has been used to investigate the effect that
water has on the nanoscale structure of protic ionic liquids (PILs) along with their precursor …

Properties of water confined in ionic liquids

K Saihara, Y Yoshimura, S Ohta, A Shimizu - Scientific reports, 2015 - nature.com
The varying states of water confined in the nano-domain structures of typical room
temperature ionic liquids (ILs) were investigated by 1H NMR and by measurements of self …

Nanostructure changes in protic ionic liquids (PILs) through adding solutes and mixing PILs

TL Greaves, DF Kennedy, N Kirby… - Physical Chemistry …, 2011 - pubs.rsc.org
The effect of adding primary n-alcohols with aliphatic chains and hexane on the
nanostructure of a series of 14 protic ionic liquids (PILs) was explored using small and wide …

Molecular dynamics study of the effect of water on hydrophilic and hydrophobic ionic liquids

T Koishi - The Journal of Physical Chemistry B, 2018 - ACS Publications
We performed molecular dynamics (MD) simulations of ionic liquid (IL)–water mixtures to
investigate the effects of water addition. The IL cation 1-butyl-3-methylimidazolium ([C4mim]) …

Direct evidence of confined water in room-temperature ionic liquids by complementary use of small-angle X-ray and neutron scattering

H Abe, T Takekiyo, M Shigemi… - The Journal of …, 2014 - ACS Publications
The direct evidence of confined water (“water pocket”) inside hydrophilic room-temperature
ionic liquids (RTILs) was obtained by complementary use of small-angle X-ray scattering …

Direct experimental observation of mesoscopic fluorous domains in fluorinated room temperature ionic liquids

FL Celso, Y Yoshida, F Castiglione, M Ferro… - Physical Chemistry …, 2017 - pubs.rsc.org
Fluorinated room temperature ionic liquids (FRTILs) represent a class of solvent media that
are attracting great attention due to their IL-specific properties as well as features stemming …

Pressure-Induced Spectral Changes of Room-Temperature Ionic Liquid, N,N-Diethyl-N-methyl-N-(2-methoxyethyl)ammonium Bis(trifluoromethylsulfonyl)imide …

Y Yoshimura, T Takekiyo, Y Imai… - The Journal of Physical …, 2012 - ACS Publications
We have investigated pressure-induced Raman spectral changes of ionic liquid, N, N-diethyl-
N-methyl-N-(2-methoxyethyl) ammonium bis (trifluoromethylsulfonyl) imide ([DEME][TFSI]) …

Confirmation of local water structure confined in ionic liquids using H/D exchange

Y Yoshimura, T Mori, K Kaneko, K Nogami… - Journal of Molecular …, 2019 - Elsevier
We investigated the local structure of water molecules confined inside ionic liquid (IL)
nanodomain structures of 1-butyl-3-methylimidazolium tetrafluoroborate,(abbreviated as …